Austenitic Stainless Steel Cladding for Nuclear Reactor Wear

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Solution Overview

Problem

Neutron-absorbing rods in nuclear reactors face wear and corrosion issues due to frequent movement and vibration, leading to a loss of neutron-absorbing capacity, with existing nitriding methods providing insufficient corrosion resistance.

Innovation Solution

A method involving hyper quenching of austenitic stainless steel blanks to maintain a metastable austenitic structure, followed by shaping and finishing without surface tensile stresses or mechanical polishing, and then hardening the surface through diffusion processes like nitriding or carburizing to enhance wear and corrosion resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If nitriding is applied to harden the outer surface of claddings, then wear resistance is improved, but corrosion resistance deteriorates

Engineering Contradiction:
Improvewear resistanceVSAvoidcorrosion resistance
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The invention changes the carbon content parameter of the austenitic stainless steel to ≤0.03%, which fundamentally alters the material's behavior during nitriding. This low carbon content prevents excessive carbide precipitation that would otherwise deplete chromium and reduce corrosion resistance, while still allowing sufficient nitrogen diffusion to achieve the desired surface hardening and wear resistance.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If frequent replacement of clusters is performed to combat wear, then wear damage is reduced, but loss of time and productivity increase

Engineering Contradiction:
Improvewear damageVSAvoidreplacement frequency
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The invention applies preliminary action by implementing a dual hardening approach (nitriding combined with low carbon content) before the claddings are put into service. This pre-treatment ensures both wear and corrosion resistance are established in advance, preventing the need for frequent replacements and extending the operational life of the neutron-absorbing rods.

Inventive Principle:
Principle #10Preliminary action

3Object-affected harmful factors

If rust prevention is required during transport and storage, then corrosion resistance must be improved, but this conflicts with the need for surface hardening

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidsurface hardening
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The low carbon content parameter (≤0.03%) fundamentally changes the material's response to nitriding, allowing the formation of a hardened surface layer that does not compromise the underlying material's corrosion resistance. This parameter change enables both surface hardening and rust prevention during transport and storage to coexist.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves improved resistance to wear and corrosion, reducing the risk of rust and maintaining the neutron-absorbing capacity of the rods, as evidenced by reduced corrosion current in potentiostatic tests and enhanced durability.

Implementation Method 1

heating the blank to a sufficient temperature and for a sufficient time to solubilise any precipitates present

Methodology Applied
Scientific EffectSolubilisation of precipitates: Diffusion

Implementation Method 2

quenching the blank at a rate allowing the austenitic structure to be maintained in metastable state at ambient temperature

Methodology Applied
Scientific EffectQuenching: Heat Treatment

Implementation Method 3

the austenitic structure to be maintained in metastable state at ambient temperature

Methodology Applied
Scientific EffectMetastable state: Metastability

Implementation Method 4

hardening the outer surface of the cladding by diffusion of one or more atomic species

Methodology Applied
Scientific EffectDiffusion of atomic species: Diffusion

Implementation Method 5

the hardening step of the outer surface of the part comprises plasma nitriding

Methodology Applied
Scientific EffectPlasma nitriding: Nitriding

Data Source

PatentUS9914986B2Method for producing, from a preform made of austenitic stainless steel with a low carbon content, a wear-resistant and corrosion-resistant cladding for a nuclear reactor, corresponding cladding and corresponding control cluster
Publication Date: 2018.03.13 AREVA NP SAS
  • US9914986B2 patent drawing
  • US9914986B2 patent drawing
  • US9914986B2 patent drawing

AI summary

A method for producing a wear-resistant and corrosion-resistant stainless steel part for a nuclear reactor is provided. This method includes steps of providing a tubular blank in austenitic stainless steel whose carbon content is equal to or lower than 0.03% by weight; shaping the blank; finishing the blank to form the cladding; hardening the outer surface of the cladding by diffusing one or more atomic species; the blank, before the providing step or during the shaping or finishing step, being subjected to at least one hyper quenching with sub-steps of: heating the blank to a sufficient temperature and for a sufficient time to solubilize any precipitates present; quenching the blank at a rate allowing the austenitic structure to be maintained in a metastable state at ambient temperature and free of precipitates.