Elastomeric Stamp Barrier Layer for Ink Blurring

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Solution Overview

Problem

Traditional lithographic techniques for patterning substrates are costly and limited in reducing feature sizes, and alternative methods like elastomeric stamping face issues with ink blurring and limited applicability due to dewetting requirements and ink absorption.

Innovation Solution

The method employs an elastomeric stamp with a barrier layer to prevent ink penetration, allowing for a wide range of inks to be used and eliminating the need for dewetting, enabling ink transfer from the edges of protruding features to substrates with higher affinity surfaces, thus improving pattern clarity and versatility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a polar solvent is used to dissolve the ink for dewetting on the elastomeric stamp, then the ink accumulates in the cavities between protruding regions, but the dewetting step leaves traces of ink on the contact surfaces causing blurring of printed features

Engineering Contradiction:
Improvepattern sharpnessVSAvoidink blurring
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The harmful dewetting step is completely removed from the process. Instead of relying on dewetting to clear ink from contact surfaces, the invention uses a barrier layer that prevents ink penetration in the first place, eliminating the source of blurring traces.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

A barrier layer is introduced as an intermediary between the elastomeric stamp and the ink solution. This barrier layer selectively prevents ink molecules from penetrating the stamp material while allowing the patterning process to proceed, thus preventing ink blurring without requiring dewetting.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If traditional lithographic techniques are used for patterning, then masks can be produced to define patterns, but the production cost increases significantly with downscaling of feature sizes and increased mask requirements

Engineering Contradiction:
Improvefeature size reductionVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention uses a master stamp with pre-formed patterns that can be replicated multiple times on different substrates. This copying approach eliminates the need for expensive lithographic masks while maintaining the ability to define precise patterns, significantly reducing production costs for small feature sizes.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The invention changes the fundamental mechanism from optical lithography to direct mechanical transfer via elastomeric stamps. This parameter change in the patterning approach allows for cost-effective production of complex patterns with small features by eliminating mask fabrication requirements.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If an elastomeric stamp without barrier layer is used, then ink can be applied to the stamp surface, but the ink penetrates the stamp material and cannot be effectively transferred to substrates with higher affinity

Engineering Contradiction:
Improveink compatibilityVSAvoidink transfer efficiency
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The barrier layer is applied selectively to specific regions of the elastomeric stamp where ink contact occurs. This local modification prevents ink penetration in those areas while maintaining the stamp's flexibility and ability to transfer patterns to substrates with higher ink affinity, thus resolving the contradiction between ink compatibility and transfer efficiency.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces ink blurring, expands ink compatibility, and allows for smaller feature sizes and more complex patterns, enhancing the resolution and versatility of the patterning process.

Implementation Method 1

the protruding feature and the bulk surface carrying a barrier layer; applying a solution of the ink and a solvent to the barrier layer

Methodology Applied
Scientific EffectPhysical barrier:

Implementation Method 2

providing a first substrate with a surface having a higher affinity for the ink than the barrier layer; transferring the ink from the contact surface of the protruding feature to the surface of the first substrate

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

applying a solution of the ink and a solvent to the barrier layer; removing the solvent from the barrier layer

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS8714082B2Method for patterning a substrate surface
Publication Date: 2014.05.06 KONINKLIJKE PHILIPS NV
  • US8714082B2 patent drawing
  • US8714082B2 patent drawing
  • US8714082B2 patent drawing

AI summary

An elastomeric stamp has a bulk surface from which protruding features extend. A barrier layer covers the bulk surface and the protruding features. After applying an ink solution to the elastomeric stamp and drying the elastomeric stamp, the elastomeric stamp is brought into contact with a surface of a first substrate. The surface of the first substrate has a high affinity with the ink molecules, which is utilized to effectively remove the ink molecules from the contact surfaces of the protruding features. Subsequently, the elastomeric stamp is brought into contact with the surface of a second substrate. Ink molecules are transferred from the edges of the protruding features to the surface of a second substrate, thus forming an ink pattern in the form of a self assembled monolayer on this surface.