Amphiphilic Star Polymers for Downhole Fluid Emulsion Stability

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Solution Overview

Problem

Conventional emulsion-based downhole fluids used in oil and gas production face issues such as phase separation, oil breakout, and weighting agent sag, leading to unstable rheological properties and inefficient drilling performance, due to limitations in emulsifier structure that do not allow for uniform droplet size optimization.

Innovation Solution

The introduction of amphiphilic star polymers and surfactants into downhole fluids, either separately or as a blend, to enhance emulsion stability and create emulsions with uniform droplet size, reducing viscosity and resistance to phase separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional surfactants are used to stabilize emulsions, then emulsion stability is improved, but droplet size uniformity deteriorates

Engineering Contradiction:
Improveemulsion stabilityVSAvoiddroplet size uniformity
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The invention changes the molecular structure parameter of the emulsifier from conventional linear surfactants to star polymers with multiple arms radiating from a central core. This structural parameter change enables simultaneous achievement of emulsion stability and uniform droplet size distribution, resolving the technical contradiction between stability improvement and droplet uniformity deterioration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses star polymer emulsifiers that combine multiple functional groups (hydrophilic arms, hydrophobic arms, and core structures) into a single composite molecular architecture. This composite structure provides both steric stabilization for emulsion stability and uniform spacing for consistent droplet size, overcoming the limitations of conventional single-function surfactants.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If emulsion stability is improved, then resistance to phase separation is improved, but viscosity increases

Engineering Contradiction:
Improveresistance to phase separationVSAvoidviscosity
Core Design Contradiction:
Stability of the object's compositionVSForce

Solution Approach 1:

The invention changes the emulsifier concentration parameter and molecular structure to achieve effective stabilization at lower concentrations. The star polymer structure provides enhanced stabilization efficiency per unit mass, reducing the total amount of emulsifier needed and thereby preventing excessive viscosity increase while maintaining high resistance to phase separation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of amphiphilic star polymers and surfactants improves the stability and rheological properties of downhole fluids, making them more resistant to phase separation and reducing the need for weighting agents, resulting in improved drilling performance and control.

Implementation Method 1

an amphiphilic star polymer and at least one surfactant are introduced, either separately or as a blend, into a downhole fluid containing emulsions in an amount effective to improve the stability of the emulsions in the downhole fluid

Methodology Applied
Scientific EffectEmulsion stabilization: Emulsion

Implementation Method 2

at least one surfactant is introduced, either separately or as a blend, into a downhole fluid containing emulsions

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS11155748B2Star polymers and methods of use for downhole fluids
Publication Date: 2021.10.26 BAKER HUGHES OILFIELD OPERATIONS LLC
  • US11155748B2 patent drawing
  • US11155748B2 patent drawing
  • US11155748B2 patent drawing

AI summary

An effective amount of amphiphilic star polymers and surfactants may be applied to downhole fluids containing oil-in-water and water-in-oil emulsions, such as drilling fluids, completion fluids, drill-in fluids, workover fluids, and remediation fluids, to stabilize the emulsions and improve rheological properties of these fluids for use in oil and gas production operations. The star polymers and surfactants may be applied to the downhole fluid separately or as a blend to generate emulsions within the fluid that have substantially uniform droplet size.