Static Charge Detection for Polyolefin Fines Control

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Solution Overview

Problem

The presence of polymer fines in gas phase reactors for polyolefin production leads to fouling and plugging issues, causing operational challenges and increased maintenance costs due to their accumulation and adherence to reactor walls and equipment.

Innovation Solution

A method involving static charge measurement using probes to detect fines accumulation, adjusting reactor operations, such as antistat addition rates and fluidization velocities, and optimizing catalyst transitions to minimize fines production and accumulation, while maintaining reactor uptime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If gas phase reactor is used for polyolefin production, then polymerization efficiency is improved, but polymer fines accumulation and fouling occur

Engineering Contradiction:
Improvepolymerization efficiencyVSAvoidpolymer fines accumulation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful static charge accumulation caused by polymer fines into a beneficial detection mechanism. By measuring static charge levels, the system can detect fines accumulation and trigger proactive interventions (such as adjusting fluidization velocity or adding antistat agents) to prevent fouling, thus turning the harmful effect into a useful diagnostic tool.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent implements a feedback control system that continuously monitors static charge levels in the reactor and adjusts operating parameters accordingly. When static charge indicates fines accumulation, the system automatically modifies fluidization velocity, temperature, or catalyst feed rates to maintain optimal conditions and prevent fouling.

Inventive Principle:
Principle #23Feedback

2Productivity

If reactor operates continuously to maintain uptime, then productivity is improved, but maintenance costs increase due to fouling

Engineering Contradiction:
Improvereactor uptimeVSAvoidmaintenance costs
Core Design Contradiction:
ProductivityVSEase of repair

Solution Approach 1:

The patent applies preliminary action by detecting polymer fines accumulation through static charge measurement before it causes severe fouling or plugging. The system proactively intervenes by adjusting operating parameters or adding antistat agents to prevent the fouling from progressing to a point requiring shutdown and maintenance, thus maintaining continuous operation.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If fluidization velocity is increased to prevent fines accumulation, then reactor efficiency is improved, but energy consumption increases

Engineering Contradiction:
Improvereactor efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent applies dynamics by continuously adjusting fluidization velocity based on real-time static charge measurements. Rather than operating at a constant high velocity, the system dynamically modulates the velocity to match actual fines accumulation conditions, maintaining reactor efficiency while minimizing energy consumption during periods when fines accumulation is controlled.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces fines-related issues, enhances reactor efficiency, and decreases maintenance costs by proactively managing fines accumulation and optimizing reactor conditions.

Implementation Method 1

measuring static charge in the reactor system

Methodology Applied
Scientific EffectStatic electricity: Electrostatics

Implementation Method 2

polymerizing olefin in the gas phase reactor into a polyolefin

Methodology Applied
Scientific EffectPolymerization: Chemical Bonding

Implementation Method 3

in presence of catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

fluidization velocities

Methodology Applied
Scientific EffectFluidization: Fluidisation

Data Source

PatentUS9433914B2Polyolefin reactor system having a gas phase reactor
Publication Date: 2016.09.06 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • US9433914B2 patent drawing
  • US9433914B2 patent drawing
  • US9433914B2 patent drawing

AI summary

A system and method for polymerizing olefin in a gas phase reactor into a polyolefin in presence of catalyst, measuring static charge in the reactor system; determining an indication of polyolefin fines in the reactor system, and adjusting operation of the reactor system in response to the indication.