Steam Cracking Coil Carburization Modeling for Lifetime Prediction

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Solution Overview

Problem

The exposure of cracking coils in steam cracking furnaces to carbon-rich gases at high temperatures leads to carburization, reducing the mechanical properties of the coil material and necessitating premature replacement, as chromium in the alloy reacts with carbon to form chromium carbides, causing embrittlement and chromium depletion.

Innovation Solution

A method to determine a carburization model for the coils, which involves measuring reference temperature values and carburized portion depths in a reference coil, using relations to characterize the growth of the carburized portion over time and temperature, allowing for the prediction of carburization depth and remaining coil lifetime without destructive examination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If coils are operated at high temperatures in carbon-rich gases, then cracking reaction efficiency is improved, but carburization of the coil material occurs, reducing mechanical properties and necessitating premature replacement

Engineering Contradiction:
Improvecracking reaction efficiencyVSAvoidcoil mechanical properties
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary action by establishing a carburization model before the coil reaches critical degradation. The model predicts future carburization depth and mechanical property degradation, enabling proactive maintenance scheduling that prevents catastrophic failure while maximizing coil utilization. The model is determined in advance using reference data and can be used to plan replacement timing optimally.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces physical examination of coil carburization with a computational model. Instead of mechanically inspecting or destructively testing the coils to assess carburization depth and mechanical properties, the system uses a mathematical model that calculates these parameters based on operating conditions and time, substituting mechanical inspection with computational prediction.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If coils are replaced based on fixed maintenance schedules, then safety is ensured, but unnecessary replacements occur, increasing downtime and costs

Engineering Contradiction:
Improvefurnace operation safetyVSAvoidfurnace downtime
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent implements feedback by continuously monitoring actual coil operating conditions (temperature, pressure, gas composition) and comparing them against the carburization model predictions. This feedback loop allows the system to adjust replacement timing based on actual coil degradation rates rather than following a rigid schedule, optimizing the balance between safety and minimizing downtime.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent applies parameter changes by using the carburization model to dynamically determine replacement timing based on predicted mechanical property degradation. Instead of using fixed time intervals, the system calculates optimal replacement points based on when the model predicts mechanical properties will fall below acceptable thresholds, allowing flexible adjustment of the replacement parameter (time) based on actual coil performance and conditions.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If destructive examination methods are used to assess carburization depth, then accurate measurement is achieved, but coil integrity is compromised and replacement becomes necessary

Engineering Contradiction:
Improvecarburization depth measurementVSAvoidcoil structural integrity
Core Design Contradiction:
Measurement precisionVSStrength

Solution Approach 1:

The patent applies copying by creating a virtual model of the coil's carburization state through mathematical calculation rather than physical measurement. The carburization model computes the depth and distribution of carburization based on operating parameters, creating a digital copy of the coil's internal state without physically touching or damaging the actual coil, thus preserving its integrity while achieving measurement objectives.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent replaces mechanical or physical examination methods with a computational approach. Instead of using techniques that physically probe or section the coil to measure carburization depth, the system substitutes these mechanical methods with mathematical modeling that predicts carburization based on thermodynamic and kinetic principles, eliminating the need for destructive physical measurement.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the evaluation of carburization without physically examining the coils, improving furnace operation efficiency, extending maintenance intervals, and reducing costs by avoiding unnecessary replacements and downtime, while optimizing the replacement timing of coils based on mechanical property thresholds.

Implementation Method 1

The exposure of the cracking coils to the carbon rich process gas at high temperatures can lead to carburisation of the material of the cracking coils, i.e. a process, wherein carbon is incorporated into the coil material

Methodology Applied
Scientific EffectCarburization: Carburizing

Implementation Method 2

carburisation of a material of the wall occurs, in particular wherein the wall material or a metal of the wall material reacts with the carbon gas led through the coil such that metal carbides are created

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS20240254400A1A method of determining a carburisation model of a coil of a steam cracking furnace
Publication Date: 2024.08.01 LINDE AG
  • US20240254400A1 patent drawing
  • US20240254400A1 patent drawing
  • US20240254400A1 patent drawing

AI summary

A method of determining a carburisation model of a coil of a steam cracking furnace, the method comprises the steps of: determining reference temperature values at reference positions of a wall of a reference coil during operation of a reference steam cracking furnace comprising a reference coil; determining reference carburised portion values of a depth at a reference point in time; determining the at least one material specific constant in dependence of the first relation and the second relation; and determining the carburisation model of the coil in dependence of the determined at least one material specific constant and further in dependence of the first relation and the second relation.