Steam Catalytic Cracking of Deasphalted Oil for Olefin Production

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Solution Overview

Problem

Conventional refinery systems require multiple complex unit operations to convert hydrocarbon feeds, such as crude oil, into valuable petrochemical products like olefins, which is inefficient and complex.

Innovation Solution

A process involving a Solvent Deasphalting Unit (SDA) to remove asphaltenes from hydrocarbon feeds, followed by steam catalytic cracking using a nano zeolite catalyst, simplifying the process and reducing the number of unit operations needed to produce olefins.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional refinery systems use multiple complex unit operations (distillation, hydrocracking, reforming, etc.) to convert crude oil to olefins, then the conversion is thorough and reliable, but the device complexity and number of unit operations increase significantly

Engineering Contradiction:
Improveconversion reliabilityVSAvoidrefinery system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple conventional refinery unit operations (distillation, deasphalting, hydrocracking, reforming, and steam cracking) into an integrated process flow where the effluent from one unit directly feeds the next unit without intermediate storage or handling. This merging reduces the overall device complexity while maintaining conversion reliability through continuous processing.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The steam catalytic cracking unit serves multiple functions: it acts as both a hydrocracking unit and a reforming unit, producing olefins, gasoline blending components, and aromatic compounds (BTX) simultaneously. This multi-functionality reduces the need for separate dedicated units for each product stream.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If conventional refinery systems employ multiple unit operations (atmospheric distillation, vacuum distillation, hydrocracking, reforming, aromatic recovery, etc.), then the product slate is comprehensive, but the number of equipment and processing steps increases

Engineering Contradiction:
Improveproduct slate versatilityVSAvoidnumber of unit operations
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent segments the crude oil feed into different boiling point ranges through atmospheric and vacuum distillation, then processes each fraction through hydrocracking and reforming units to produce specific product slates. This segmentation allows comprehensive product coverage while organizing the complex process into manageable stages.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent utilizes parameter changes in the hydrocracking and reforming units (temperature, pressure, catalyst type) to adjust the product slate versatility. By modifying operating parameters rather than adding more units, the system achieves comprehensive product coverage with fewer equipment pieces.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional refinery systems use multiple complex processing steps (distillation, hydrocracking, reforming, aromatic recovery, steam cracking), then the olefin production is maximized, but the processing time and operational complexity increase

Engineering Contradiction:
Improveolefin production yieldVSAvoidprocessing time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent implements continuous processing where crude oil flows continuously through distillation, deasphalting, hydrocracking, reforming, and steam cracking units without batch interruptions. This continuity maximizes olefin production yield while reducing total processing time compared to batch operations.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent performs preliminary deasphalting and hydrocracking operations before the final steam cracking step that produces olefins. By preparing the feedstock in advance through these preliminary actions, the main olefin production step can operate at optimal conditions with maximum efficiency and reduced processing time.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the yield and production of valuable products like olefins with fewer equipment and process units, achieving higher efficiency and productivity compared to traditional methods.

Implementation Method 1

The SDA comprises a solvent that reacts with the hydrocarbon feed

Methodology Applied
Scientific EffectSolvent reaction: Solvation

Implementation Method 2

steam catalytically cracking the deasphalted oil stream in the steam catalytic cracking system in the presence of steam and a nano zeolite cracking catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS11708314B2Systems and processes for producing olefins from crude oil
Publication Date: 2023.07.25 SAUDI ARABIAN OIL CO
  • US11708314B2 patent drawing
  • US11708314B2 patent drawing
  • US11708314B2 patent drawing

AI summary

A process for producing olefins from the hydrocarbon feed includes introducing the hydrocarbon feed into a Solvent Deasphalting Unit (SDA) to remove asphaltene from the hydrocarbon feed producing a deasphalted oil stream, wherein the SDA comprises a solvent that reacts with the hydrocarbon feed, and the deasphalted oil stream comprises from 0.01 weight percent (wt. %) to 18 wt. % asphaltenes; introducing the deasphalted oil stream into a steam catalytic cracking system; steam catalytically cracking the deasphalted oil stream in the steam catalytic cracking system in the presence of steam and a nano zeolite cracking catalyst to produce a steam catalytic cracking effluent; and separating the olefins from the steam catalytic cracking effluent.