Steam Cracking Feed Preheating Through Steam Heat Exchange

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Solution Overview

Problem

Conventional steam cracking processes face challenges in efficiently preheating and evaporating hydrocarbon feedstocks using electric heaters, particularly for hydrocarbons with wide boiling ranges and high fouling potential, leading to equipment fouling and heater failure.

Innovation Solution

A method and system that utilizes steam as a heat medium to preheat and superheat hydrocarbon feedstocks, with at least 90% of the heat for preheating provided by steam, minimizing direct electrical heating to reduce fouling risks, using a two-stage preheating process with different steam pressures and temperatures in feed preheaters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If electric heaters are used to preheat and evaporate hydrocarbon feedstocks, then the heating efficiency is improved, but equipment fouling increases and heater failure occurs

Engineering Contradiction:
Improveheating efficiencyVSAvoidequipment fouling
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent introduces steam as an intermediary heat transfer medium between the electric heater and the hydrocarbon feedstock. The electric heater heats the steam, and the steam then preheats and evaporates the hydrocarbon feedstock in a separate heat exchange process. This intermediary approach prevents direct contact between the heating element and the hydrocarbon, eliminating fouling on the heater surface while maintaining efficient heat transfer through the steam's high thermal conductivity and phase change capabilities.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Loss of energy

If conventional fuels are used for heating in steam cracking furnaces, then the heat balance is maintained, but carbon dioxide emissions increase

Engineering Contradiction:
Improveheat balanceVSAvoidcarbon dioxide emissions
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The patent replaces the conventional chemical combustion system (burning fossil fuels) with an electrical heating system. Electric heaters generate heat through resistive heating or other electrical conversion methods, eliminating the combustion process that produces carbon dioxide emissions. The system maintains the required heat balance by using electricity to generate the necessary thermal energy for steam generation and process heating, thereby decoupling heat production from carbon emissions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If hydrocarbon feedstock is preheated to high temperatures before mixing with steam, then the evaporation rate is improved, but fouling potential increases

Engineering Contradiction:
Improveevaporation rateVSAvoidfouling potential
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary heating action by preheating the hydrocarbon feedstock to an intermediate temperature (not the final high cracking temperature) before mixing with steam. This preliminary preheating reduces the temperature gap between the feedstock and the steam, improving the evaporation rate when they mix. The feedstock is then rapidly evaporated upon contact with the high-temperature steam, achieving complete vaporization without requiring the feedstock to be preheated to the final high temperature that would cause fouling.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method allows for efficient preheating and evaporation of hydrocarbon feedstocks without significant fouling, ensuring stable operation of electrical steam cracking furnaces and producing petroleum-derived products with reduced environmental impact.

Implementation Method 1

at least 90% of a heat amount used in said preheating the feed stream until its combination with the superheated dilution steam is provided by transferring heat from steam to the hydrocarbon feed stream

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

steam cracking the steam cracking feed stream using a steam cracking arrangement operated with electric energy

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 3

heated further to a temperature closer to a cracking temperature sufficient to carry out an endothermic reaction for cracking the hydrocarbons

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Implementation Method 4

The cracked mixture may thereafter be fed to a heat exchanger to rapidly quench the cracked mixture to minimize undesired post-cracking reactions

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentEP4588992A1Method and system for steam cracking
Publication Date: 2025.07.23 LINDE AG
  • EP4588992A1 patent drawingFigure 1
  • EP4588992A1 patent drawingFigure 2
  • EP4588992A1 patent drawingFigure 3

AI summary

There is provided a method of steam cracking one or more hydrocarbons, the method comprising preheating a liquid hydrocarbon feed stream (1) containing the one or more hydrocarbons to provide a preheated hydrocarbon feed stream (2), superheating a dilution steam stream (3) to provide superheated dilution steam stream (4), combining the preheated hydrocarbon feed stream (2) and the superheated dilution steam stream (4) to provide a gaseous steam cracking feed stream (6), and steam cracking the gaseus steam cracking feed stream (6) using a steam cracking arrangement (F) operated with electric energy, wherein at least 90% of of a heat amount used in said preheating the hydrocarbon stream (1) until its combination with the superheated dilution steam (4) is provided by transferring heat from steam to the hydrocarbon feed stream (1). A corresponding system (100, 200, 300, 400) for steam cracking is also provided.