Steam Injection System for Polyolefin Catalyst Deactivation

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Solution Overview

Problem

Traditional deactivation materials in polyolefin manufacturing systems, when injected at high flow rates, lead to operational issues and increased costs due to accumulation in recovery systems, reducing efficiency and increasing operational and material costs.

Innovation Solution

A steam injection system is used to deactivate catalysts and additives in the polyolefin manufacturing process, with a control system adjusting the steam flow based on polymerization characteristics to optimize deactivation efficiency and reduce excess steam usage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional deactivation materials are injected at high flow rates to ensure complete deactivation of catalysts and additives, then deactivation effectiveness is improved, but operational issues and costs increase due to accumulation in recovery systems

Engineering Contradiction:
Improvedeactivation effectivenessVSAvoidaccumulation in recovery system
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The system dynamically adjusts the flow rate of deactivation material based on real-time monitoring of catalyst and additive levels in the polymerization reactor. The controller receives feedback signals indicating the presence and concentration of these components, then automatically modulates the injection rate to match actual deactivation needs, preventing both under-deactivation and excessive accumulation in downstream recovery systems

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

A feedback control system continuously monitors the polymerization process by detecting catalyst and additive concentrations in the reactor effluent. This information is fed back to the controller, which adjusts the deactivation material injection rate accordingly, creating a closed-loop system that optimizes deactivation effectiveness while minimizing harmful accumulation in recovery equipment

Inventive Principle:
Principle #23Feedback

2Reliability

If high flow rates of deactivation materials are used to prevent undesired polymerization downstream, then operational reliability is improved, but system efficiency decreases and operational costs increase

Engineering Contradiction:
Improveprevention of undesired polymerizationVSAvoidsystem efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The injection system transitions from static high-flow-rate operation to dynamic flow rate adjustment based on actual process conditions. The controller modulates the deactivation material flow to match the instantaneous concentration of catalyst and additive in the slurry, ensuring adequate deactivation while minimizing excess material that would reduce system efficiency and increase operational costs

Inventive Principle:
Principle #15Dynamics

3Reliability

If high flow rates of deactivation materials are injected to ensure complete deactivation, then deactivation completeness is improved, but material costs increase

Engineering Contradiction:
Improvedeactivation completenessVSAvoiddeactivation material consumption
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The feedback control system monitors catalyst and additive concentrations in real-time and adjusts the deactivation material injection rate to match actual requirements. This prevents wasteful consumption of deactivation material by injecting only the amount needed to completely deactivate the catalyst and additives present in the slurry, rather than using excessive fixed high flow rates

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system changes the flow rate parameter of deactivation material injection based on detected catalyst and additive levels. By dynamically adjusting this parameter rather than maintaining a constant high flow rate, the system achieves complete deactivation while minimizing material consumption and associated costs

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The steam injection system reduces operational issues and costs by varying steam flow according to catalyst and additive levels, preventing accumulation and improving production efficiency, while also reducing capital expenditures by eliminating the need for traditional deactivation material equipment.

Implementation Method 1

injecting steam into a mixture to deactivate certain components of the mixture, such as a catalyst, a co-catalyst, other additives, or any combination thereof

Methodology Applied
Scientific EffectChemical reaction (deactivation): Chemical Bonding

Data Source

PatentUS9617358B2System and method for polymerization
Publication Date: 2017.04.11 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • US9617358B2 patent drawing
  • US9617358B2 patent drawing
  • US9617358B2 patent drawing

AI summary

Techniques are provided for polymerization. A polymerization method may include polymerizing a monomer in a polymerization reactor to produce a slurry comprising polyolefin particles and a diluent, flowing the slurry out of the polymerization reactor through an outlet of the polymerization reactor, receiving the slurry from the outlet into a slurry handling system, conveying a first mixture from the slurry handling system to a diluent and monomer recovery system, and injecting steam into the first mixture downstream of the slurry handling system using a steam injection system.