High Strength Steel Sheet Delayed Fracture Resistance

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Solution Overview

Problem

High strength steel sheets with high ductility and delayed fracture resistance are needed for vehicle components like bumper reinforcing members and shock absorbers, but existing methods increase the fraction of retained austenite, leading to delayed fracture due to internal stress and hydrogen diffusion.

Innovation Solution

A cold rolled steel sheet and hot dip galvanized steel sheet with a composition of 0.05 to 0.3% C, 0.3 to 1.6% Si, 4.0 to 7.0% Mn, 0.5 to 2.0% Al, 0.01 to 0.1% Cr, 0.02 to 0.1% Ni, 0.005 to 0.03% Ti, 5 to 30 ppm B, and 0.01 to 0.03% Sb, processed through hot finish rolling, coiling, pickling, and either continuous annealing or batch annealing to achieve a tensile strength of 980 MPa or more and elongation of 28% or more, with improved delayed fracture resistance by adding Al to stabilize retained austenite.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high strength and high elongation are increased by increasing the fraction of retained austenite, then tensile strength and ductility are improved, but delayed fracture resistance deteriorates due to internal stress and hydrogen diffusion

Engineering Contradiction:
Improvetensile strengthVSAvoiddelayed fracture resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by adding specific elements (Al: 0.01-2.0%, Ti: 0.003-0.06%, B: 0.003-0.03%, Nb: 0.003-0.06%, V: 0.003-0.06%) to modify the properties of retained austenite. This allows achieving high tensile strength (980 MPa or more) and elongation (28% or more) while improving delayed fracture resistance through controlled parameter changes in the steel composition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of retained austenite (20-40% by area ratio) combined with martensite and/or bainite. This composite structure at the micro level provides both high strength and improved delayed fracture resistance by combining the ductility benefits of retained austenite with the strength characteristics of martensite/bainite

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If high strength steel is used for vehicle components, then vehicle weight is reduced, but delayed fracture occurs due to hydrogen diffusion in retained austenite

Engineering Contradiction:
Improvevehicle weightVSAvoiddelayed fracture
Core Design Contradiction:
Weight of moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful effect of retained austenite (which normally promotes delayed fracture) into a beneficial feature by controlling its fraction (20-40%) and stabilizing it through alloying elements. The retained austenite continues to provide ductility through TRIP effect while the harmful delayed fracture is suppressed by the optimized composition and microstructure

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent introduces intermediary elements (Al, Ti, B, Nb, V) that act as mediators between the retained austenite and hydrogen. These elements modify the chemical and physical properties of the steel matrix, reducing hydrogen diffusion rates and trapping hydrogen, thereby preventing delayed fracture while maintaining the benefits of retained austenite

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If conventional manufacturing methods are used to produce steel with high retained austenite, then strength and ductility are improved, but delayed fracture resistance remains poor

Engineering Contradiction:
ImproveformabilityVSAvoiddelayed fracture resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent optimizes multiple parameters simultaneously: chemical composition (adding Al, Ti, B, Nb, V), microstructure (controlling retained austenite fraction at 20-40%), and heat treatment conditions (cooling rates, annealing temperatures). This multi-parameter optimization achieves both excellent formability through drawing and high delayed fracture resistance, overcoming the limitations of conventional single-parameter approaches

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The steel sheets exhibit enhanced tensile strength, elongation, and delayed fracture resistance, allowing for increased ductility and stability, making them suitable for vehicle components that require bending and drawing without significant crack formation, thus improving vehicle safety and lightweight body stability.

Implementation Method 1

adding Al to stabilize retained austenite

Methodology Applied
Scientific EffectSolid solution strengthening: Solid Solution Strengthening

Implementation Method 2

the retained austenite formed as above is caused to transform into martensite during plastic deformation, thereby increasing strength as well as ductility by alleviating stress concentration

Methodology Applied
Scientific EffectTransformation Induced Plasticity (TRIP): Phase Change

Implementation Method 3

processed through hot finish rolling, coiling, pickling, and either continuous annealing or batch annealing

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 4

The delayed fracture is generally in the form of cracks, which are caused by the diffusion of hydrogen atoms or molecules under high residual stress

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS9109273B2High strength steel sheet and hot dip galvanized steel sheet having high ductility and excellent delayed fracture resistance and method for manufacturing the same
Publication Date: 2015.08.18 POHANG IRON & STEEL CO LTD

AI summary

A cold rolled steel sheet and a hot dip galvanized steel sheet, which have high strength and elongation, such as a tensile strength of 980 MPa or more and an elongation of 28% or more, and excellent delayed fracture resistance, and manufacturing methods thereof. The cold rolled steel sheet has a composition including 0.05 to 0.3 weight percent C, 0.3 to 1.6 weight percent Si, 4.0 to 7.0 weight percent Mn, 0.5 to 2.0 weight percent Al, 0.01 to 0.1 weight percent Cr, 0.02 to 0.1 weight percent Ni and 0.005 to 0.03 weight percent Ti, 5 to 30 ppm B, 0.01 to 0.03 weight percent Sb, 0.008 weight percent or less S, balance Fe and impurities. The hot dip galvanized steel sheet has a hot dip galvanized layer or a hot dip galvannealed layer on the cold rolled steel sheet.