Steel Sheet Microstructure for LME Resistance and Formability

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Solution Overview

Problem

There is a need for a steel sheet that balances high strength with excellent press-formability and liquid metal embrittlement (LME) cracking resistance, particularly in spot welded parts, as existing steel sheets do not adequately address these requirements.

Innovation Solution

A steel sheet with a specific chemical composition and microstructure is developed, including a surface Al concentration to Si concentration ratio of 0.2 or less, reduced nonrecrystallized ferrite, and the addition of Ti to fix nitrogen as TiN, which improves LME cracking resistance and press-formability. The steel sheet has a microstructure comprising ferrite, tempered martensite, retained austenite, and bainite, with a hot dip galvanized or galvannealed layer for enhanced properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high strength steel sheet is used to increase tensile strength, then collision safety is improved, but press-formability deteriorates

Engineering Contradiction:
Improvetensile strengthVSAvoidpress-formability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition parameters (C: 0.15-0.30%, Si: 0.30-1.50%, Mn: 1.40-3.49%, Al: 0.30-1.50%, Ti: 0.001-0.100%) and microstructure parameters (ferrite volume fraction 1-50%, retained austenite 5-30%, tempered martensite 10-60%, bainite 10-40%) to achieve both high tensile strength (980 MPa or more) and excellent press-formability (total elongation 10% or more, hole expansion ratio 20% or more). This multi-parameter optimization resolves the contradiction between strength and formability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of four phases: ferrite, retained austenite, tempered martensite, and bainite. Each phase contributes different properties: ferrite provides ductility, retained austenite provides TRIP effect for work hardening, tempered martensite provides strength, and bainite provides a balance of strength and ductility. This composite microstructure simultaneously achieves high tensile strength and excellent press-formability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If Si is added to obtain retained austenite, then press-formability is improved, but LME cracking resistance deteriorates

Engineering Contradiction:
Improvepress-formabilityVSAvoidLME cracking resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies local quality by creating a non-uniform Al/Si distribution at the steel sheet surface. By controlling the area ratio of regions with AlS/SiS ratio of 0.2 or less to be 50% or less, the surface develops localized Al-enriched regions that provide LME cracking resistance while Si-enriched regions maintain press-formability. This spatial differentiation of composition resolves the contradiction between the two opposing requirements.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the compositional parameters by adding Al (0.30-1.50%) in addition to Si (0.30-1.50%) and controlling their surface concentration ratio. This parameter modification allows the steel to achieve both press-formability (through Si-induced retained austenite) and LME cracking resistance (through Al-enriched surface regions) simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If Al is added to improve LME cracking resistance, then weldability is improved, but press-formability deteriorates due to inhibition of ferrite recrystallization

Engineering Contradiction:
ImproveLME cracking resistanceVSAvoidpress-formability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces Ti (0.001-0.100%) as an intermediary element that forms TiN inclusions. These TiN inclusions act as nucleation sites for ferrite recrystallization during hot rolling, counteracting the recrystallization inhibition caused by Al. This intermediary mechanism allows Al to be added for LME cracking resistance without sacrificing press-formability, as the TiN particles facilitate the recrystallization process that Al would otherwise suppress.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The steel sheet achieves high tensile strength, elongation, and hole expandability, while significantly improving LME cracking resistance in spot welded parts, making it suitable for automotive applications.

Implementation Method 1

addition of Ti to fix nitrogen as TiN, which improves LME cracking resistance and press-formability

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

a steel microstructure in a range of 1/8 thickness to 3/8 thickness centered on 1/4 thickness from the surface comprising ferrite, tempered martensite, retained austenite, and bainite

Methodology Applied
Scientific EffectPhase transformation: Phase Change

Implementation Method 3

high strength hot dip galvanized steel sheet which is hot dip galvanized on its surface

Methodology Applied
Scientific EffectHot dip galvanization: Deposition (physical)

Data Source

PatentUS12098440B2Steel sheet and method for producing same
Publication Date: 2024.09.24 NIPPON STEEL CORPORATION
  • US12098440B2 patent drawing
  • US12098440B2 patent drawing
  • US12098440B2 patent drawing

AI summary

Provided are a steel sheet having a predetermined chemical composition, and a steel microstructure comprising, by vol %, ferrite: 1 to 50%, ratio of nonrecrystallized ferrite in the ferrite: 0 to 50%, tempered martensite: 1% or more, retained austenite: 5% or more, fresh martensite: 0 to 10%, total of pearlite and cementite: 0 to 5%, and balance: bainite, and, when analyzing the surface by an EPMA, an area ratio of regions with an AlS/SiS ratio of 0.2 or less is 50% or less, and a tensile strength is 980 MPa or more, and a method for producing the same.