Isothermal Nucleic Acid Amplification via Stem-Loop DNA Linker

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Solution Overview

Problem

Isothermal nucleic acid amplification methods often suffer from non-specific amplifications due to DNA polymerase's chain replacement activity, which complicates sequencing processes and affects the accuracy of sequencing results, especially in specialized sequencing technologies like Oxford Nanopore.

Innovation Solution

An isothermal self-amplification method using a DNA linker with a palindromic complementary sequence that forms a stem-loop structure, allowing for primer-independent amplification by DNA polymerase, resulting in a folding-complementary, single-stranded DNA product without GC bias, suitable for two-generation sequencing libraries and improved sequencing accuracy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional isothermal amplification methods are used, then amplification can be achieved, but non-specific amplifications occur due to DNA polymerase chain replacement activity

Engineering Contradiction:
Improveamplification specificityVSAvoidnon-specific amplification
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The DNA linker is designed with a palindromic complementary sequence that forms a stem-loop structure, enabling the DNA fragment to self-trigger amplification without external primers. The 3' end of the linker folds back and hybridizes to the template, creating a self-sufficient initiation mechanism that eliminates non-specific amplification caused by free primers

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The DNA linker acts as an intermediary element that bridges the template DNA and the amplification process. By incorporating the palindromic sequence into the linker itself rather than using separate primers, the system achieves specific amplification initiation without the harmful effects of free primers

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If rolling circle amplification is used for sequencing, then sequencing accuracy is improved, but the process becomes complicated and amplification heterogeneity is reduced

Engineering Contradiction:
Improvesequencing accuracyVSAvoidamplification process complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The invention extracts the essential function of primer-mediated initiation from the complex RCA process by embedding the primer-like palindromic sequence directly into the DNA linker. This simplifies the overall process while maintaining the ability to generate homogeneous amplification products suitable for sequencing

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The DNA linker serves multiple functions: it acts as a structural element for fragment assembly, contains the palindromic sequence for self-triggered amplification initiation, and provides the template for homogeneous product generation. This multi-functionality eliminates the need for separate primers and complex RCA protocols

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Productivity

If primers are added for amplification, then amplification can be initiated, but non-specific amplifications occur

Engineering Contradiction:
Improveamplification efficiencyVSAvoidamplification specificity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The DNA fragment itself serves as the primer through its palindromic complementary sequence. The 3' end folds back and hybridizes to the template, initiating amplification without requiring external primers. This self-service mechanism maintains high efficiency while ensuring specificity

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The palindromic sequence is pre-built into the DNA linker during library preparation. This preliminary incorporation of the amplification trigger eliminates the need for separate primer addition steps and prevents non-specific amplification from the outset

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables rapid, effective amplification of target fragments under isothermal conditions, increasing sequencing frequency and accuracy, and eliminating non-specific amplifications, with the amplification product being a long, continuous complementary single-stranded DNA suitable for high-throughput sequencing.

Implementation Method 1

a linear nucleic acid fragment having a palindromic complementary sequence, which itself spontaneously forms a stem-loop structure to trigger the extension amplification by the DNA polymerase

Methodology Applied
Scientific EffectStem-loop structure formation: Self-Assembly

Implementation Method 2

the reagent comprises a DNA polymerase with chain replacement activity

Methodology Applied
Scientific EffectDNA polymerase chain replacement activity: Enzyme

Data Source

PatentEP3470529B1Nucleic acid isothermal self-amplification method
Publication Date: 2022.05.18 LU XINHUA
  • EP3470529B1 patent drawingFigure 1~2
  • EP3470529B1 patent drawingFigure 3~4
  • EP3470529B1 patent drawingFigure 5

AI summary

Provided is a nucleic acid isothermal self-amplification method comprising, adding suitable palindrome complementary sequences at both ends of a target template to form a stem-loop structure spontaneously, and providing reagents and conditions as needed to perform self-amplification. The method does not require addition of additional amplification primers. The reagent comprises a DNA polymerase having a strand displacement activity. The method does not rely on exogenous amplification primers for amplification, has a constant amplification temperature without a complex temperature control equipment, and achieves rapid amplification. The amplification product is a long single-stranded DNA of a continuous complementary sequence and can be applied to special occasions. In addition, the amplification has no GC bias.