Step-Graded AlGaN Buffer for III-V on Silicon Lattice Mismatch

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Solution Overview

Problem

Existing methods for forming III-V compound layers on silicon substrates often result in wafer defects such as cracking due to lattice constant mismatches, leading to low-quality layers.

Innovation Solution

A method involving the formation of a step-graded aluminum gallium nitride buffer layer on a silicon substrate, with a first buffer layer of aluminum nitride and subsequent sub-layers of aluminum gallium nitride with decreasing aluminum content, followed by epitaxial growth of gallium nitride layers to mitigate lattice mismatch and stress.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a III-V compound layer is formed directly on a silicon substrate, then manufacturing cost is reduced, but wafer defects such as cracking occur due to lattice constant mismatch

Engineering Contradiction:
Improvemanufacturing costVSAvoidwafer defect density
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A buffer layer comprising multiple sub-layers with graded aluminum content is introduced as an intermediary between the silicon substrate and the III-V compound layer. This buffer layer gradually transitions the lattice constant from silicon to the III-V compound, preventing direct lattice mismatch and eliminating cracking defects while maintaining cost benefits of using silicon substrates

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The buffer layer utilizes parameter changes in aluminum content across multiple sub-layers, where each sub-layer has a different aluminum concentration. This gradual parameter change creates a lattice constant gradient that bridges the mismatch between silicon and III-V compounds, resolving the contradiction between cost and reliability

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If existing methods are used to form III-V compound layers on silicon substrates, then cost is reduced, but layer quality deteriorates due to stress and defects

Engineering Contradiction:
Improvesubstrate costVSAvoidlayer quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The buffer layer is segmented into multiple sub-layers, each with progressively changing aluminum content. This segmentation allows for controlled stress distribution and gradual lattice transition, significantly improving layer quality while maintaining silicon substrate cost advantages

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The buffer layer is constructed as a composite structure with varying material composition (different aluminum content in each sub-layer). This composite approach enables precise control of lattice constants and stress states, achieving high layer quality on cost-effective silicon substrates

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the growth of high-quality III-V compound layers on silicon substrates with reduced defect density and allows for thicker layers, improving the quality and reliability of semiconductor devices like LEDs and RF devices.

Implementation Method 1

due to lattice constant mismatches between the III-V compound layer and the silicon substrate

Methodology Applied
Scientific EffectLattice constant mismatch:

Implementation Method 2

epitaxial growth of gallium nitride layers

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS9691855B2Method of growing a high quality III-V compound layer on a silicon substrate
Publication Date: 2017.06.27 ENNOSTAR CORP
  • US9691855B2 patent drawing
  • US9691855B2 patent drawing
  • US9691855B2 patent drawing

AI summary

The present disclosure involves a method of fabricating a semiconductor device. A surface of a silicon wafer is cleaned. A first buffer layer is then epitaxially grown on the silicon wafer. The first buffer layer contains an aluminum nitride (AlN) material. A second buffer layer is then epitaxially grown on the first buffer layer. The second buffer layer includes a plurality of aluminum gallium nitride (AlxGa1-xN) sub-layers. Each of the sub-layers has a respective value for x that is between 0 and 1. A value of x for each sub-layer is a function of its position within the second buffer layer. A first gallium nitride (GaN) layer is epitaxially grown over the second buffer layer. A third buffer layer is then epitaxially grown over the first GaN layer. A second GaN layer is then epitaxially grown over the third buffer layer.