Stevioside-Rebaudioside D Complex Solubility

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Solution Overview

Problem

Rebaudioside D has low solubility in water, making it difficult to prepare beverage concentrates and beverages with sufficient sweetness and organoleptic properties, as only about 300 to 450 ppm can be solubilized at 23°C after extended stirring, which is impractical for commercial production.

Innovation Solution

Combining rebaudioside D with stevioside in various ratios in an aqueous solution at room or elevated temperatures to create a stevioside/rebaudioside D complex, significantly increasing rebaudioside D solubility up to 10,000 to 25,000 ppm, allowing for higher concentration solutions to be prepared in reasonable timeframes suitable for commercial manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If rebaudioside D is combined with stevioside in various ratios in an aqueous solution, then rebaudioside D solubility is significantly increased (50 to 125-fold), but the complexity of the composition increases

Engineering Contradiction:
Improverebaudioside D solubilityVSAvoidcomposition complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent combines rebaudioside D with stevioside to form a composite sweetening composition. This composite material approach allows the beneficial solubility enhancement from stevioside to be harnessed while maintaining the desirable taste profile of rebaudioside D, achieving both improved solubility and acceptable product quality

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the ratio parameters of stevioside to rebaudioside D in the composition to achieve maximum solubility enhancement. By carefully controlling these compositional parameters, the patent achieves 50 to 125-fold increases in solubility while managing the complexity through defined ratio ranges

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If rebaudioside D is used at higher concentrations to provide desired sweetness, then sweetness level improves, but solubility limitations prevent achieving sufficient concentrations in practical timeframes

Engineering Contradiction:
Improvesweetness concentrationVSAvoidpreparation speed
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

Stevioside acts as an intermediary substance that facilitates the dissolution of rebaudioside D. By introducing stevioside into the system, the patent creates a medium that enables much higher concentrations of rebaudioside D to be achieved rapidly, without requiring extended stirring times

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent prepares stevioside/rebaudioside D complex compositions in advance that are pre-formulated to provide rapid solubility enhancement. This preliminary preparation of optimized compositions allows for quick dissolution and immediate achievement of target sweetness concentrations in commercial production

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The stevioside/rebaudioside D complex enhances rebaudioside D solubility 50 to 125-fold, enabling the production of high-concentration steviol glycoside solutions that are stable and practical for commercial use, improving taste profiles and sweetness levels in beverages.

Implementation Method 1

Combining rebaudioside D with stevioside in various ratios in an aqueous solution at room or elevated temperatures to create a stevioside/rebaudioside D complex, significantly increasing rebaudioside D solubility

Methodology Applied
Scientific EffectComplexation: Chemical Bonding

Data Source

PatentUS20250017246A1Sweetening compositions
Publication Date: 2025.01.16 PEPSICO INC
  • US20250017246A1 patent drawing
  • US20250017246A1 patent drawing
  • US20250017246A1 patent drawing

AI summary

This disclosure provides aqueous steviol glycoside compositions as well as syrups and beverages comprising these compositions. In certain embodiments, the aqueous steviol glycoside composition comprises water and a sweetening composition, wherein the sweetening composition is solubilized in the water and comprises a stevioside composition and rebaudioside D.