Shallow Trench Isolation Liner for Void-Free High-Aspect-Ratio Fill

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Solution Overview

Problem

Existing techniques struggle to adequately fill trenches with high aspect ratios in semiconductor devices, leading to incomplete gap-filling and the formation of unwanted voids, which can result in defects and inadequate isolation between active areas, affecting yield.

Innovation Solution

A method involving the use of a flowable dielectric layer deposited at low temperatures, followed by in-situ curing and thermal annealing processes to convert it into a silicon dioxide network, forming a conformal liner layer with uneven nitrogen distribution, which fills high aspect ratio trenches without voids and reduces manufacturing time and cost.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional gap-filling techniques are used to fill trenches, then the filling process is simpler and faster, but incomplete gap-filling occurs leading to voids and defects in high aspect ratio trenches

Engineering Contradiction:
Improvegap-filling completenessVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The gap-filling process is divided into multiple sequential deposition steps with alternating dielectric materials (first dielectric layer, second dielectric layer, third dielectric layer). Each layer is deposited to a controlled thickness and patterned, creating a segmented fill structure that eliminates voids in high aspect ratio trenches while maintaining process control

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different dielectric materials are used in different regions and layers of the trench fill. The first, second, and third dielectric layers have different properties optimized for their specific positions, with each layer providing localized functionality that contributes to complete void-free filling of the trench structure

Inventive Principle:
Principle #3Local quality

2Productivity

If trench width is decreased to increase circuit density, then circuit density increases, but aspect ratio of trenches increases leading to incomplete gap-filling and void formation

Engineering Contradiction:
Improvecircuit densityVSAvoidgap-filling completeness
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The trench fill is segmented into multiple alternating dielectric layers deposited in sequential steps. This segmentation allows complete filling of narrow high aspect ratio trenches by building up material in controlled increments, ensuring no voids form even when trench width is reduced to increase circuit density

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The trench is filled with a composite structure of multiple dielectric materials (first dielectric layer, second dielectric layer, third dielectric layer) with different properties. This composite approach enables complete filling of high aspect ratio trenches while providing functional differentiation across layers

Inventive Principle:
Principle #40Composite materials

3Reliability

If multiple separate processes are used to form liner layer and isolation structure, then each process can be optimized independently, but manufacturing time and cost increase

Engineering Contradiction:
Improveprocess optimizationVSAvoidmanufacturing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The liner layer formation and isolation structure creation are merged into a single integrated process sequence. The alternating dielectric layers serve dual functions: forming the liner structure and providing the isolation fill, eliminating the need for separate liner deposition and isolation filling processes

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The alternating dielectric layers perform multiple functions simultaneously: the first dielectric layer forms part of the liner structure, the second dielectric layer provides isolation fill, and the third dielectric layer completes the liner and isolation. This multi-functionality reduces the number of separate process steps required

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively fills trenches with high aspect ratios, preventing voids and defects, ensuring reliable isolation and reducing manufacturing time and costs by integrating the liner layer formation with the isolation structure.

Implementation Method 1

a flowable dielectric layer is deposited at low temperatures

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

followed by in-situ curing and thermal annealing processes to convert it into a silicon dioxide network

Methodology Applied
Scientific EffectThermal annealing: Annealing

Data Source

PatentUS12464786B2Semiconductor device
Publication Date: 2025.11.04 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12464786B2 patent drawing
  • US12464786B2 patent drawing
  • US12464786B2 patent drawing

AI summary

A structure of a semiconductor device includes a substrate, an isolation structure, and a liner layer. The isolation structure is embedded in the substrate. The isolation structure has a bottom surface and a sidewall. The liner layer is between the substrate and the isolation. A first portion of the liner layer in contact with the sidewall of the isolation structure has a nitrogen concentration lower than a second portion of the liner layer in contact with the bottom surface of the isolation structure.