Zero-Emissions Refinery for Stillage Recovery

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Solution Overview

Problem

Current methods for handling raw stillage streams in alcohol distillation processes result in significant air emissions and water contamination, with existing thermal oxidizers generating additional environmental and energy problems.

Innovation Solution

A closed-loop energy refinery and purification system that eliminates the need for thermal oxidizers, achieving zero emissions by synergistically processing raw stillage to produce clean water, renewable natural gas, and other valuable by-products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If thermal oxidizers are used to treat off-gas from stillage processing, then VOCs are destroyed, but air contamination and energy consumption increase

Engineering Contradiction:
ImproveVOC destructionVSAvoidair contamination
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful VOC stream into a beneficial fuel source by using it as feedstock for anaerobic digestion, which produces methane for energy generation. This eliminates the need for thermal oxidizers while converting the harmful waste stream into a useful resource, thereby destroying VOCs without generating air contamination or requiring additional energy input

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent extracts and separates the liquid stillage stream before it can be converted to harmful VOCs through evaporation. By using decanter centrifuges to separate solids from liquids and then directing the liquid stream to anaerobic digestion, the system prevents VOC formation at the source while capturing organic compounds for beneficial use

Inventive Principle:
Principle #2Taking out (Extraction)

2Object-affected harmful factors

If thermal oxidizers are used to combust waste vapor stream, then off-gas is treated, but CO2, NOx, and SOx emissions are generated

Engineering Contradiction:
Improveoff-gas treatmentVSAvoidCO2, NOx, and SOx emissions
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent converts the waste vapor stream into a beneficial fuel source by using it as feedstock for anaerobic digestion, which produces methane for energy generation. This eliminates the need for combustion-based treatment that generates CO2, NOx, and SOx emissions, while still achieving off-gas treatment through biological conversion

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Use of energy by moving object

If digester produces anaerobic generated gas stream, then methane is produced for heating, but uncollected CH4 and contaminates are sent to TO requiring additional fuel

Engineering Contradiction:
Improvemethane utilizationVSAvoiduncollected CH4
Core Design Contradiction:
Use of energy by moving objectVSLoss of energy

Solution Approach 1:

The patent implements a self-sustaining system where the anaerobic digester produces methane that is used to heat the digester itself and power the facility. The system captures and utilizes all produced gas, eliminating the need for external thermal oxidizers and additional fuel inputs. The digester serves its own energy needs, creating a closed-loop system that minimizes energy loss

Inventive Principle:
Principle #25Self-service

4Productivity

If open type environment processing is used, then stillage separation is achieved, but water discharge contamination occurs

Engineering Contradiction:
Improvestillage separationVSAvoidwater discharge contamination
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the contaminated water discharge into a beneficial resource by using it as feedstock for algae cultivation. The nutrients in the stillage water promote algae growth, which is then harvested and used as additional feedstock for anaerobic digestion. This eliminates water discharge contamination while enhancing productivity through additional methane production

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively recovers clean water and valuable by-products while eliminating air emissions and water discharge, enhancing the efficiency and effectiveness of the separation process and creating a self-sustaining facility at net zero emissions.

Implementation Method 1

decanter centrifuge liquid solid separation

Methodology Applied
Scientific EffectCentrifugal separation: Centrifugal Separation

Implementation Method 2

anaerobic digester converting the liquid stillage stream into a methane rich stream

Methodology Applied
Scientific EffectAnaerobic digestion: Anaerobic Digestion

Implementation Method 3

TOs use natural gas to combust a lean waste vapor stream

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS12209040B2Zero-emissions refinery system and method for liquid waste stream recovery of clean water and valuable by-products
Publication Date: 2025.01.28 SIEGEL STANLEY MICHAEL
  • US12209040B2 patent drawing
  • US12209040B2 patent drawing
  • US12209040B2 patent drawing

AI summary

In producing ethanol suitable for alcoholic beverages or fuels, the separation of stillage involves a complicated treatment system necessary to meet stringent air emissions standards and effluent discharge limits. High water content of stillage creates a difficult process mass flow balance configuration resulting in a large power demand and footprint. The present invention simplifies the production and usage of valuable stillage by-products and reduces net energy consumption and emissions to zero with a novel system and method involving a step sequence of: a solid liquid separation; at least one digester arrangement; a closed gas separation system; algae grow nutrient up-take system; a nutrient separation system; an ultra-filtration water system enabling the off-take by-products to be used by the system and an off-take market for the by-products and its purified water. All produced by-products including carbon dioxide (CO2) and methane (CH4) are used in the system or exported as products.