Stimuli-Responsive Release Liner for Adhesive Recycling

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Solution Overview

Problem

Conventional packaging materials, including labels, pose challenges for recycling and reuse due to the presence of non-removable release liners, which hinder the recycling process and contribute to waste accumulation.

Innovation Solution

A layered construction incorporating a stimuli-responsive polymer that reacts to non-ambient stimuli, allowing for the removal and recycling of layers, such as a release liner or adhesive, by depolymerizing in response to specific triggers like heat, light, or chemicals, enabling the separation of layers and facilitating recycling or reuse.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional label construction with a release liner is used, then the adhesive is protected from premature bonding, but the release liner cannot be removed and recycled, creating waste

Engineering Contradiction:
Improveadhesive protectionVSAvoidrelease liner waste
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The release liner is made with a stimuli-responsive polymer that changes its bonding properties in response to specific stimuli (heat, light, chemicals). Under normal storage conditions, the polymer maintains low bonding to protect the adhesive. When recycling is needed, applying the appropriate stimulus causes the polymer to change its bonding characteristics, allowing clean separation of the release liner from the adhesive layer for independent recycling.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If a release liner is included to protect the adhesive, then the adhesive functions properly during storage, but the release liner must be disposed of in the waste stream

Engineering Contradiction:
Improveadhesive protection during storageVSAvoidrecycling process
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The release liner's bonding properties are made dynamic rather than static. The stimuli-responsive polymer allows the release liner to transition between a protective state (low bonding during storage and use) and a separable state (high bonding change when stimulus is applied). This dynamic behavior enables the same material to serve its protective function during manufacturing and use, then facilitate easy separation during recycling without requiring different materials for different stages.

Inventive Principle:
Principle #15Dynamics

3Loss of substance

If the release liner is made removable for recycling, then waste is reduced, but the adhesive bonding strength may be compromised

Engineering Contradiction:
Improvematerial recyclabilityVSAvoidadhesive bonding
Core Design Contradiction:
Loss of substanceVSStrength

Solution Approach 1:

The bonding strength parameter of the release liner is made changeable through stimulus response. During normal use, the polymer maintains optimal bonding strength to ensure reliable adhesive attachment. When recycling is required, applying the specific stimulus (heat, light, or chemical) causes the polymer's bonding parameters to change, enabling clean separation without compromising the adhesive's bonding strength during its functional service life.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution allows for the efficient removal and recycling of packaging components, reducing waste and promoting sustainability by enabling the separation of layers without damaging the underlying materials, thus enhancing the recyclability and degradability of packaging materials.

Implementation Method 1

the functional layer includes a stimuli-responsive polymer... the stimuli-responsive polymer reacts to at least one specific, non-ambient, stimuli selected from the group consisting of base, acid, oxidizing agent, reducing agent, non-ionizing radiation, ultrasound, acid derived from a photoacid, ultraviolet light, infrared light, visible light, heat, and combinations thereof

Methodology Applied
Scientific EffectStimuli-responsive polymer reaction:

Data Source

PatentUS20240352286A1Layered constructions with removable layers
Publication Date: 2024.10.24 BOISE STATE UNIVERSITY
  • US20240352286A1 patent drawing
  • US20240352286A1 patent drawing
  • US20240352286A1 patent drawing

AI summary

Layered constructions, such as those used in pressure sensitive adhesive constructions and release liner constructions, are disclosed having a functional layer that is capable of removal. Methods of utilizing the layered constructions are also disclosed.