Stirrer Power Control for (Meth)acrylonitrile Polymerization

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

In solution polymerization for preparing (meth)acrylonitrile-based polymers used in carbon fibers, high viscosity reaction solutions lead to increased power consumption and variations in polymer physical properties due to inefficient mixing, resulting in higher production costs and reduced polymerization conversion ratios.

Innovation Solution

Performing solution polymerization under specific power consumption conditions based on the viscosity of the reaction solution, with 1-5 kW/m3 for viscosities of 0.1-250 poise and 8-13 kW/m3 for viscosities of 250-450 poise, using a (meth)acrylonitrile-based monomer and reaction solvent in a reactor equipped with a suitable stirrer, to ensure efficient mixing and controlled heat management.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the stirrer constantly consumes power to mix the reaction solution, then the mixing is maintained, but the power consumption increases unnecessarily when the viscosity is low

Engineering Contradiction:
Improvemixing qualityVSAvoidpower consumption
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The patent applies dynamic control of the stirrer by adjusting its rotation speed according to the reaction solution's viscosity changes during polymerization. The stirrer operates at different speeds in different stages: higher speed when viscosity is low to ensure mixing, and lower speed when viscosity increases to reduce energy consumption while maintaining adequate mixing. This dynamic adjustment resolves the contradiction between maintaining mixing quality and reducing unnecessary energy consumption.

Inventive Principle:
Principle #15Dynamics

2Ease of operation

If the stirrer operates at high power to handle high viscosity, then mixing is maintained, but production costs increase due to unnecessary energy consumption

Engineering Contradiction:
Improvemixing qualityVSAvoidproduction cost
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The patent implements dynamic power adjustment of the stirrer based on real-time viscosity monitoring. During early polymerization stages when viscosity is low, the stirrer operates at lower power to avoid unnecessary energy consumption. When viscosity increases to higher levels, the power is increased only to the extent needed to maintain adequate mixing. This staged power adjustment directly reduces production costs while maintaining mixing quality throughout the process.

Inventive Principle:
Principle #15Dynamics

3Productivity

If the reaction solution viscosity increases during polymerization, then polymerization conversion ratio increases, but mixing becomes inefficient causing variations in polymer physical properties

Engineering Contradiction:
Improvepolymerization conversion ratioVSAvoidmixing efficiency
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent employs dynamic stirrer speed adjustment that responds to viscosity changes during polymerization. As the reaction progresses and viscosity increases, the stirrer speed is increased to compensate for the thicker solution, maintaining adequate mixing efficiency. This dynamic response allows the system to achieve high polymerization conversion ratios while preventing the mixing inefficiency that would otherwise occur at high viscosity levels, thereby avoiding variations in polymer physical properties.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements a feedback control mechanism where the stirrer operation is continuously adjusted based on the reaction solution's viscosity state. The system monitors viscosity changes during polymerization and provides feedback to adjust stirrer speed accordingly. This feedback loop ensures that mixing efficiency is maintained throughout the polymerization process even as viscosity increases, allowing high conversion ratios to be achieved without compromising product uniformity.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces energy consumption, maintains consistent physical properties of the polymer, and increases the final polymerization conversion ratio, enhancing the production efficiency and quality of (meth)acrylonitrile-based polymers for carbon fibers.

Implementation Method 1

Solution polymerization is performed by smoothly mixing a reaction solution in a reactor using a stirrer

Methodology Applied
Scientific EffectStirring: Stirring

Implementation Method 2

adding a reaction solution comprising a (meth)acrylonitrile-based monomer and a reaction solvent to a reactor to perform solution polymerization

Methodology Applied
Scientific EffectPolymerization: Chemical Bonding

Data Source

PatentUS11046792B2Method of preparing (meth)acrylonitrile-based polymer for preparing carbon fiber
Publication Date: 2021.06.29 LG CHEM LTD

AI summary

The present invention relates to a method of preparing a (meth)acrylonitrile-based polymer for preparing a carbon fiber, which comprises adding a reaction solution comprising a (meth)acrylonitrile-based monomer and a reaction solvent to a reactor to perform solution polymerization, performing solution polymerization under a condition in which a power consumption of the reactor is 1 to 5 kW/m3 when the reaction solution in the reactor has a viscosity of 0.1 poise or more and 250 poise or less, and performing solution polymerization under a condition in which a power consumption of the reactor is 8 to 13 kW/m3 when the reaction solution in the reactor has a viscosity of more than 250 poise and 450 poise or less.