Shallow Trench Isolation Liner Height Control via Wet Etching

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Solution Overview

Problem

Current dry etching methods fail to consistently achieve a uniform height for the silicon nitride liner in shallow trench isolation (STI) structures, leading to voids when the liner is too high or loss of protection for the spin-on-glass layer when it's too low, making it difficult to form an ideal STI.

Innovation Solution

The method employs sequential wet etching steps to control the etching intensity, forming a first and second liner layer, followed by selective wet etching to expose the substrate and adjust the liner height, ensuring uniformity, and then fills the trench with a second oxide using high-density plasma to form a shallow trench isolation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If dry etching method is used to form the silicon nitride liner, then the etching process can be performed, but the liner height becomes non-uniform

Engineering Contradiction:
Improveetching process capabilityVSAvoidliner height uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the etching method from dry etching to wet etching, altering the process parameters to achieve both manufacturability and uniform liner height. The wet etching process uses chemical solutions that provide more uniform etching rates across the substrate surface, resolving the contradiction between process capability and precision.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the physical/mechanical dry etching process with a chemical wet etching process. This substitution allows the etching to proceed through chemical reactions that are more uniform and controllable, thereby achieving better liner height uniformity while maintaining the etching function.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If the silicon nitride liner level is too high, then the liner provides adequate protection, but voids appear in the oxide filling

Engineering Contradiction:
Improveliner protection functionVSAvoidoxide filling quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

By changing from dry to wet etching, the patent achieves more precise control over liner height, preventing it from being too high. This parameter control ensures that the oxide filling can proceed without creating voids, while the liner still maintains adequate protective function.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If the silicon nitride liner level is too low, then the oxide filling is easier, but the spin-on-glass layer loses protection and is damaged

Engineering Contradiction:
Improveoxide filling processVSAvoidspin-on-glass layer protection
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent uses wet etching to precisely control the liner height parameter, ensuring it is neither too high nor too low. This precise parameter control maintains the protective function for the spin-on-glass layer while still allowing proper oxide filling, resolving the contradiction between ease of manufacture and reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the formation of a shallow trench isolation with a uniform and ideal liner height, preventing voids and protecting the spin-on-glass layer, thereby improving the reliability of the STI structure.

Implementation Method 1

performing a first wet etching to remove part of the first oxide and part of the first liner layer to expose the substrate

Methodology Applied
Scientific EffectWet etching:

Implementation Method 2

performing a second wet etching to remove part of the second liner layer so that the second liner layer is lower than the surface of the substrate

Methodology Applied
Scientific EffectWet etching:

Implementation Method 3

performing a third wet etching to remove part of the first oxide and part of the first liner layer

Methodology Applied
Scientific EffectWet etching:

Implementation Method 4

the high-density plasma would usually fail to fill the trench with an oxide

Methodology Applied
Scientific EffectHigh-density plasma: Plasma

Data Source

PatentUS8207065B2Method for forming a shallow trench isolation
Publication Date: 2012.06.26 NAN YA TECH
  • US8207065B2 patent drawing
  • US8207065B2 patent drawing
  • US8207065B2 patent drawing

AI summary

A method for forming a shallow trench isolation includes providing a substrate with a trench, a first liner layer and a second liner layer sequentially in the trench with a first oxide filling the trench, performing a first wet etching to remove part of the first oxide and part of the first liner layer to expose the substrate, performing a second wet etching to remove part of the second liner layer so that the second liner layer is lower than surface of the substrate, performing a third wet etching to remove part of the first oxide and part of the first liner layer, and filling the trench with a second oxide to form a shallow trench isolation.