Storage-Stable Dye Salts Using Alkanolamines

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Solution Overview

Problem

Conventional dye compositions face stability issues during storage and transportation, leading to precipitation and disruptions in pumping systems, and they contribute to high water-treating costs due to high carbon content in effluents.

Innovation Solution

A storage-stable dye composition comprising a compound of formula (I) with a coupling component and an alkanolamine, such as triisopropanolamine or dimethylethanolamine, which maintains stability across a wide temperature range and reduces sedimentation and crystallization, thereby preventing disruptions and effluent issues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional aqueous dye solutions are used, then dyeing function is provided, but storage stability deteriorates leading to precipitation during transportation and storage

Engineering Contradiction:
Improvestorage stabilityVSAvoidprecipitation prevention
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the chemical parameter by replacing conventional amine salts with alkanolamine salts (specifically triisopropanolamine or dimethylethanolamine). This parameter change in the salt structure fundamentally alters the storage stability characteristics, preventing precipitation across a wide temperature range from -20°C to 50°C without requiring additional solubilizers.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If solubilizers are added to improve storage stability, then precipitation is prevented, but carbon content in effluents increases leading to high water-treating costs

Engineering Contradiction:
Improvestorage stabilityVSAvoidcarbon content in effluents
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and eliminates the need for additional solubilizers from the dye composition. By using alkanolamine salts intrinsically, the formulation removes the harmful solubilizer components that would otherwise increase carbon content in effluents and require expensive water treatment, while maintaining storage stability.

Inventive Principle:
Principle #2Taking out (Extraction)

3Temperature

If frozen dye compositions are stored, then transportation is enabled, but stability problems occur during thawing and pumping

Engineering Contradiction:
Improvefreezing temperature rangeVSAvoidthawing stability
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The patent changes the physical-chemical parameters of the dye composition through alkanolamine salt formation, which prevents crystallization and maintains stability during freezing and thawing cycles. This enables the dye to be stored frozen at -20°C and remain stable during subsequent thawing and pumping operations without precipitation or degradation.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10392514B2Storage-stable dye solutions
Publication Date: 2019.08.27 ARCHROMA IP GMBH
  • US10392514B2 patent drawing
  • US10392514B2 patent drawing
  • US10392514B2 patent drawing

AI summary

The present invention relates to storage-stable dye salts, solutions and compositions thereof a process for their preparation and their use for dyeing and/or printing substrates.