Transparent Stretchable Electronics With Liquid Metal Grid Conductors

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Solution Overview

Problem

Conventional flexible transparent conducting films (TCFs) face limitations such as low transmittance, brittleness, poor flexibility, short bending fatigue life, complex and expensive fabrication, and high raw material costs, making them unsuitable for applications requiring mechanical deformation without conductivity loss.

Innovation Solution

The development of stretchable electronics with a liquid metal coating on a stretchable substrate, specifically using a biphasic metallic grid pattern on a polydimethylsiloxane (PDMS) substrate, achieved through laser patterning to enhance stretchability, transmittance, and transparency, while maintaining conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional flexible TCFs are used, then electrical conductivity is maintained, but mechanical flexibility and stretchability are poor

Engineering Contradiction:
Improvemechanical flexibilityVSAvoidconductivity under strain
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The continuous metal film is segmented into discrete metallic islands separated by gaps. This segmentation allows the substrate to deform elastically under strain while the metal islands maintain electrical connectivity through the conductive polymer matrix, resolving the contradiction between mechanical flexibility and conductivity reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the physical state of the metal from continuous solid film to discrete liquid metal droplets that can deform and reconfigure. This parameter change enables the material to accommodate mechanical strain while maintaining electrical conductivity through the liquid metal's ability to flow and reform connections.

Inventive Principle:
Principle #35Parameter changes

2Strength

If TCF thickness is increased to withstand mechanical deformation, then mechanical robustness is improved, but optical transmittance decreases

Engineering Contradiction:
Improvemechanical robustnessVSAvoidoptical transmittance
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

By segmenting the metal into discrete islands rather than a continuous thick film, the patent reduces the total metal coverage area while maintaining mechanical integrity. This allows light to pass through the gaps between islands, achieving both mechanical robustness and high optical transmittance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The TCF structure incorporates a porous architecture with gaps between metallic islands and a conductive polymer matrix. This porous structure reduces light blocking while maintaining mechanical strength through the distributed island architecture and elastic substrate.

Inventive Principle:
Principle #31Porous materials

3Ease of manufacture

If conventional TCF fabrication methods are used, then manufacturing process is established, but fabrication complexity and cost are high

Engineering Contradiction:
Improvefabrication simplicityVSAvoidfabrication process complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent replaces complex multi-step sputtering and patterning processes with a simplified solution involving spin-coating of conductive polymer and droplet deposition of liquid metal. This substitution of manufacturing methods dramatically reduces fabrication complexity and cost.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses inexpensive materials such as conductive polymer electrolytes and common liquid metal alloys (Ga-In-Sn) instead of expensive ITO or complex multilayer structures. This approach reduces raw material costs and simplifies the fabrication process.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides high optical transmittance (>85%) and mechanical robustness, allowing the electronics to remain functional and imperceptible under strain, suitable for applications like wearable computing and soft robotics.

Implementation Method 1

laser patterning to enhance stretchability, transmittance, and transparency

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS11923103B2Stretchable electronics and methods of making the same
Publication Date: 2024.03.05 CARNEGIE MELLON UNIV
  • US11923103B2 patent drawing
  • US11923103B2 patent drawing
  • US11923103B2 patent drawing

AI summary

A stretchable and transparent electronic structure may generally include a stretchable elastomer layer; optionally, a metal adhesion layer on top of the stretchable elastomer layer; a metal alloying layer on top of the metal adhesion layer; and a liquid metal, wherein the structure is colorless and transparent when viewed under visible light. Methods of making the stretchable and transparent electronic structure are also described.