Stretchable Electrooptical Devices Using Ionic Conducting Gel Layers

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Solution Overview

Problem

Conventional liquid crystal electrooptical devices are stiff and brittle, making them unsuitable for flexible and wearable applications, as they struggle to achieve high electrical conductance and optical transmittance simultaneously, and are prone to fracture under mechanical stress.

Innovation Solution

The use of ionic conductors, specifically polymer gels, replaces electronic conductors in liquid crystal devices, enabling stretchable and flexible electrooptical devices with improved mechanical and electrical switching properties, allowing for biaxial stretching and reduced driving voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If electronic conductors (such as ITO) are used in liquid crystal devices, then high electrical conductance is achieved, but optical transmittance is reduced and mechanical flexibility is lost

Engineering Contradiction:
Improveelectrical conductanceVSAvoidoptical transmittance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent replaces electronic conductors (ITO) with ionic conductors (polymer gels) to eliminate the trade-off between electrical conductance and optical transmittance. The ionic conducting gel layers conduct electricity through ion transport while maintaining high optical transparency, as ionic conduction does not involve electron reflection or absorption of light.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses composite polymer gel materials that combine ionic conductivity with optical transparency. The gel layers are formed from polymer networks (such as polyacrylamide or polyvinyl alcohol) crosslinked with borax, creating a composite structure that enables both ionic conduction and light transmission.

Inventive Principle:
Principle #40Composite materials

2Reliability

If electronic conductors (such as ITO) are used in liquid crystal devices, then high electrical conductance is achieved, but mechanical flexibility and stretchability are reduced

Engineering Contradiction:
Improveelectrical conductanceVSAvoidmechanical flexibility
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent replaces brittle inorganic electronic conductors with soft, flexible ionic conducting polymer gels. The gel layers can be stretched and deformed without fracture, enabling flexible and wearable liquid crystal devices while maintaining electrical conductance through ion transport.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses thin film gel layers (5-50 micrometers thick) that are inherently flexible and can conform to curved surfaces. These gel films replace rigid ITO electrodes, enabling the liquid crystal device to be bent, stretched, and integrated into flexible displays and wearable electronics.

Inventive Principle:
Principle #30Flexible shells and thin films

3Illumination intensity

If ionic conductors are used in liquid crystal devices, then optical transmittance and mechanical flexibility are improved, but driving voltage requirements increase

Engineering Contradiction:
Improveoptical transmittanceVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the ionic conductivity of the gel layers by adjusting polymer concentration, crosslinking density, and ionic liquid content. By carefully controlling these parameters, the gel layers achieve sufficient ionic conductivity to drive the liquid crystal at reduced voltages (5-20V), balancing optical transparency with acceptable driving voltage requirements.

Inventive Principle:
Principle #35Parameter changes

4Strength

If ionic conductors are used in liquid crystal devices, then stretchability is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovestretchabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent uses photopolymerization to form the gel layers, allowing precise control of gel properties through light exposure parameters. This manufacturing approach enables consistent production of stretchable gel electrodes with controlled ionic conductivity and mechanical properties, simplifying the fabrication process despite the complexity of the gel materials.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The devices maintain electrooptical performance under stretch, offering increased transparency and reduced threshold voltage for switching, enabling applications in wearable displays and other flexible formats.

Implementation Method 1

ionic conductors are readily being highly stretchable and transparent... ionic conductors can enable devices of unusual characteristics

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

Liquid crystals have enabled many electrooptical devices, including liquid-crystal displays, universal optical phase modulators, beam steering devices

Methodology Applied
Scientific EffectElectrooptical effect: Electro-Optic Effects

Implementation Method 3

polymer gels are employed as transparent ionic conductors... the ionic conducting gel layer includes an elastomeric hydrogel

Methodology Applied
Scientific EffectElasticity: Elasticity

Data Source

PatentUS11175544B2Stretchable electrooptical and mechanooptical devices comprising a liquid crystal cell disposed between first and second ionic conducting gel layers
Publication Date: 2021.11.16 PRESIDENT & FELLOWS OF HARVARD COLLEGE
  • US11175544B2 patent drawing
  • US11175544B2 patent drawing
  • US11175544B2 patent drawing

AI summary

A stretchable electrooptical device includes a liquid crystal cell disposed between first and second ionic conducting gel layers; and first and second electronic conductors in electrical contact with the first and second ionic conducting gel layers, respectively, said first and second electronic conductors connectable to an external voltage source.