Multilayer Structural Pigment with Protective Oxide Coating

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Solution Overview

Problem

Current multilayer thin film pigments require a large number of layers to achieve high-chroma omnidirectional structural colors, leading to high production costs and susceptibility to color fading and shifting when exposed to sunlight, particularly ultraviolet light.

Innovation Solution

A multilayer thin film pigment with a protective oxide coating that reduces photocatalytic activity by at least 50%, using a process involving oxide precursors like silicon, aluminum, zirconium, titanium, or cerium to deposit a weather-resistant layer, allowing for a minimal number of layers while maintaining color stability and resistance to environmental factors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a large number of thin film layers are used to achieve high-chroma omnidirectional structural colors, then the color properties are improved, but the production cost increases and the manufacturing complexity increases

Engineering Contradiction:
Improvecolor propertiesVSAvoidnumber of layers
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent divides the protective coating into multiple functional layers: a base protective layer and an optional overcoat layer with different properties. This segmentation allows each layer to perform specific functions (UV protection, color enhancement, durability) rather than requiring all functions in a single thick layer, thereby achieving high-chroma omnidirectional structural colors with reduced overall layer count and complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses composite material structures combining organic protective coatings with inorganic oxide layers (such as silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, or cerium oxide). This composite approach provides both the protective functions and optical properties needed for high-chroma omnidirectional structural colors, reducing the need for numerous separate layers while maintaining or improving color performance.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If a large number of thin film layers are used to achieve high-chroma omnidirectional structural colors, then the color properties are improved, but the production cost increases

Engineering Contradiction:
Improvecolor propertiesVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The protective coating is segmented into essential base layers and optional overcoat layers. This allows manufacturers to produce cost-effective versions with just the base protective layer while offering premium versions with additional overcoat layers for enhanced properties, thereby providing flexibility in production costs while maintaining high-chroma omnidirectional structural color performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent optimizes the thickness and composition parameters of the protective layers to achieve the desired optical effects with minimal material usage. By carefully controlling layer thicknesses and material compositions, the patent achieves high-chroma omnidirectional structural colors with reduced layer count, thereby lowering production costs while maintaining color properties.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If the pigment is exposed to ultraviolet light and sunlight, then the pigment provides color, but the pigment undergoes fading and color changing

Engineering Contradiction:
Improvecolor reflectionVSAvoidcolor stability
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent applies protective coatings containing UV-absorbing materials and antioxidants to the pigment surface before exposure to sunlight and ultraviolet light. These coatings preemptively block or neutralize the harmful effects of UV radiation and oxidative processes, preventing fading and color changing while allowing the pigment to maintain its color reflection properties under illumination.

Inventive Principle:
Principle #9Preliminary anti-action

Solution Approach 2:

The protective coating acts as an intermediary layer between the pigment and the environment (sunlight, UV radiation, moisture). This intermediate layer absorbs or reflects harmful UV radiation, provides antioxidants to prevent oxidative degradation, and maintains a stable interface between the pigment and external conditions, thereby protecting the pigment's color stability while preserving its optical properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If a protective coating is added to reduce photocatalytic activity, then the weather resistance is improved, but the device complexity increases

Engineering Contradiction:
Improveweather resistanceVSAvoidcoating structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines organic protective polymers with inorganic oxide nanoparticles or layers (silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, or cerium oxide) to create a composite protective coating. This composite structure provides weather resistance, UV protection, and reduced photocatalytic activity through the synergistic effects of the combined materials, achieving high reliability without requiring excessively complex multi-layer structures.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The protective coating is designed to perform multiple functions simultaneously: UV protection, antioxidant protection, adhesion enhancement, and surface protection. By integrating these multiple protective functions into a single or few coating layers, the patent achieves improved weather resistance while minimizing the increase in device complexity compared to multiple separate protective layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a high-chroma omnidirectional structural color with minimal layer requirements, significant reduction in photocatalytic activity, and enhanced weather resistance, resulting in a cost-effective and stable pigment that maintains color consistency when viewed from different angles and exposed to broadband electromagnetic radiation.

Implementation Method 1

reduces a relative photocatalytic activity of the pigment by at least 50%

Methodology Applied
Scientific EffectPhotocatalysis: Catalysis

Implementation Method 2

pigments can exhibit fading, changing of color, etc. when exposed to sunlight, and in particular to ultraviolet light

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Implementation Method 3

reflects a band of electromagnetic radiation having a predetermined full width at half maximum (FWHM) of less than 300 nm

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 4

high-chroma omnidirectional structural color

Methodology Applied
Scientific EffectReflection: Reflection

Data Source

PatentUS10870740B2Non-color shifting multilayer structures and protective coatings thereon
Publication Date: 2020.12.22 VIAVI SOLUTIONS INC(US)
  • US10870740B2 patent drawing
  • US10870740B2 patent drawing
  • US10870740B2 patent drawing

AI summary

An omnidirectional structural color pigment having a protective coating. The pigment has a first layer of a first material and a second layer of a second material, the second layer extending across the first layer. In addition, the pigment reflects a band of electromagnetic radiation having a predetermined full width at half maximum (FWHM) of less than 300 nm and a predetermined color shift of less than 30° when the pigment is exposed to broadband electromagnetic radiation and viewed from angles between 0 and 45°. The pigment has a weather resistant coating that covers an outer surface thereof and reduces a relative photocatalytic activity of the pigment by at least 50%.