Structural Supercapacitor Interfaces With Gradient Electrolyte
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Solution Overview
Problem
Existing structural supercapacitors face a trade-off between improving electrochemical performance and mechanical load-bearing performance, limiting their energy-storage capacity and efficiency.
Innovation Solution
The integration of a stable conjugated redox polymer and carbon-based compound coating on carbon fiber-based structures, combined with a functionally graded solid-state electrolyte configuration, enhances both energy-storage and mechanical load-bearing capabilities.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If structural supercapacitors use conventional electrode and electrolyte designs, then mechanical load-bearing efficiency is maintained, but electrochemical performance and energy-storage capacity are limited
Solution Approach 1:
The patent applies local quality by creating a gradient configuration in the structural electrolyte where different regions have different compositions optimized for their specific functions. The electrolyte contains a first region with high ionic conductivity near the electrode interface and a second region with high mechanical modulus away from the interface, allowing each region to perform its primary function optimally without compromising the other.
Solution Approach 2:
The patent employs composite materials by combining carbon fiber-based electrodes with conjugated redox polymer coatings and graphene oxide, and by creating a composite structural electrolyte that integrates both ionic conduction and mechanical load-bearing capabilities. This composite approach enables the material to simultaneously achieve enhanced electrochemical performance and mechanical strength.
2Reliability
If the structural electrolyte is optimized for high ionic conductivity, then electrochemical performance improves, but mechanical modulus decreases
Solution Approach 1:
The patent applies segmentation by dividing the structural electrolyte into distinct functional regions: a first region adjacent to the electrode optimized for ionic conductivity with higher salt concentration and polymer content, and a second region away from the electrode optimized for mechanical modulus with lower salt concentration and polymer content. This segmentation allows each region to specialize in its primary function.
Solution Approach 2:
The patent implements parameter changes by systematically varying the concentration of salt and polymer content across the electrolyte gradient. The first region has higher concentrations of ionic conductivity-enhancing components, while the second region has lower concentrations, creating a continuous parameter transition that balances electrochemical and mechanical requirements.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution achieves a significant increase in specific capacitance and tensile strength, along with improved ionic conductivity and mechanical modulus, resulting in energy-storage capacity comparable to mono-functional supercapacitors while maintaining mechanical integrity under deformation.
Implementation Method 1
carbon fiber-based electrodes coated with a stable conjugated redox polymer and graphene oxide
Implementation Method 2
a gradient configuration for the structural electrolyte that optimizes ionic conductivity and mechanical modulus
Data Source
AI summary
Embodiments of the presently disclosed technology provide improved structural supercapacitors that increase multi-functional efficiency (i.e., improve energy-storage and mechanical load-bearing capacity/performance). Structural supercapacitors of the present technology achieve such improvements in part by focusing on interfaces between structural electrodes and structural electrolytes. For example, the present technology can provide improved structural electrodes by coating carbon fiber-based structures with a uniquely stable conjugated redox polymer and a carbon-based compound. Such coating (at the interface between the structural electrode and a structural electrolyte) can improve and tensile strength for the structural electrode. The present technology can also provide improved structural electrolytes that leverage a “gradient” configuration for a structural electrolyte where composition of the structural electrolyte is tuned such that regions of the structural electrolyte immediately adjacent to structural electrodes incorporate a higher concentration of an ion-conducting polymer and salt than “middle” regions of the structural electrolyte.


