Structured Catalyst Monolith Arrays for Uniform Endothermic Reactions

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Solution Overview

Problem

Conventional heat transfer methods for endothermic reactions, such as convection, conduction, and radiation, are inefficient and result in temperature disparities within catalyst beds, leading to high energy consumption and potential damage from hot spots.

Innovation Solution

A structured catalyst system comprising electrically conductive monoliths with ceramic coatings, connected by a monolith bridge, is heated via electrical resistance, allowing controlled temperature profiles and reduced hot spot formation through sintering or oxidizing treatment, enabling efficient energy use and catalyst reduction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional heat transfer methods (convection, conduction, radiation) are used to heat the catalyst bed, then the system can maintain continuous operation, but heat transfer efficiency is low and temperature disparities occur leading to hot spots and high energy consumption

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidtemperature uniformity
Core Design Contradiction:
Use of energy by moving objectVSTemperature

Solution Approach 1:

The patent replaces conventional thermal convection and conduction heating mechanisms with electrical resistance heating. Electrically conductive particles or structured catalysts are heated directly by passing electric current through them, converting electrical energy to thermal energy at the catalyst itself rather than relying on external heat transfer through walls or gas convection. This substitution eliminates heat transfer resistance and temperature gradients, achieving uniform heating throughout the catalyst bed.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Use of energy by stationary object

If electrically conductive particles are used in a fixed bed reactor, then internal heating can be achieved, but the system requires high electrical power input and complex electrical connection infrastructure

Engineering Contradiction:
Improveinternal heating capabilityVSAvoidelectrical connection infrastructure
Core Design Contradiction:
Use of energy by stationary objectVSDevice complexity

Solution Approach 1:

The patent merges the catalyst particles with electrically conductive materials into a single integrated component. The catalyst is either coated on conductive particles or the conductive particles themselves serve as the catalyst support, eliminating the need for separate heating elements and complex electrical connection infrastructure. This consolidation simplifies the system while maintaining effective internal heating capability.

Inventive Principle:
Principle #5Merging (Combining)

3Productivity

If conventional tubular reformers with external heating are used, then the reactor can handle large scale production, but heat transfer through tube walls is the rate limiting step and energy consumption is high

Engineering Contradiction:
Improvelarge scale production capabilityVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent replaces external thermal heating through tube walls with internal electrical resistance heating of the catalyst particles themselves. This eliminates the heat transfer bottleneck through tube walls and catalyst bed convection, allowing large scale production with significantly reduced energy consumption since heat is generated directly where needed rather than being transferred from an external source.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If the amount of catalytically active material is increased to improve reaction rate, then productivity increases, but the overall energy consumption and reactor size increase

Engineering Contradiction:
Improvereaction rateVSAvoidoverall energy consumption
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent changes the thermal parameters of the system by implementing internal electrical heating, which dramatically improves heat transfer efficiency to the catalyst particles. This allows the reaction to proceed at high rates with much lower overall energy input because the heat is delivered directly to the catalyst without losses through convection, conduction, or radiation barriers. The effective utilization of energy enables reduced catalyst loading while maintaining high productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves high-temperature, high-pressure product gas output with reduced emissions and energy consumption, while maintaining catalyst integrity and controlling the reaction front.

Implementation Method 1

wherein said electrical power supply is dimensioned to heat at least part of said first and second monoliths to a temperature of at least 500° C. by passing an electrical current through said macroscopic structure

Methodology Applied
Scientific EffectElectrical resistance heating: Joule Heating

Implementation Method 2

said array has been produced by a process comprising the steps of i) providing the electrically conductive materials of the first monolith, the second monolith and the monolith bridge in the form of three separate entities, and ii) joining the separate entities together by a method comprising a step of sintering or oxidizing treatment

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS12415174B2Endothermic reaction of a feed gas heated by resistance heating
Publication Date: 2025.09.16 GRUNDFOS HLDG
  • US12415174B2 patent drawing
  • US12415174B2 patent drawing
  • US12415174B2 patent drawing

AI summary

Array including a first and a second monolith of a structured catalyst for carrying out an endothermic reaction of a feed gas, wherein: a) the first and second monolith include a macroscopic structure of a first and second electrically conductive material; b) each of said first and second monoliths has a number of flow channels formed therein for conveying feed gas through the monoliths; c) the array includes at least a first and a second conductor electrically connected to said first and second monoliths, respectively, and to an electrical power supply, d) the first and second monolith are electrically connected by a monolith bridge; e) the array is configured to direct an electrical current to run from the first conductor through the first monolith to a second end, then through the bridge, and then through the second monolith to the second conductor.