Structured Catalyst Resistance Heating for On-Demand Synthesis Gas

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Solution Overview

Problem

Small-scale synthesis gas production is challenging due to energy-intensive reactions and the toxicity of carbon monoxide, making storage and handling difficult.

Innovation Solution

A structured catalyst comprising electrically conductive macroscopic structures with connectors, supporting catalytically active material, is used in a reactor system with a pressure shell and heat insulation, enabling on-demand gas production and efficient heat delivery through resistance heating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If large chemical plants are used for synthesis gas production, then production capacity is sufficient, but plant size and complexity increase

Engineering Contradiction:
Improvesynthesis gas production capacityVSAvoidplant size
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The catalyst is divided into multiple modular macroscopic structures (e.g., honeycomb monoliths) that can be individually manufactured and then assembled together. Each macroscopic structure contains catalytically active material in its cells, allowing the system to achieve large production capacity through parallel arrangement of standardized modules rather than requiring a single large complex plant

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent embeds multiple functional elements within nested structures: catalytically active material is deposited on the walls of honeycomb cells, which are arranged in macroscopic structures that are then assembled into arrays. This nested organization allows high surface area catalyst support in compact volumes, achieving large production capacity without proportional increase in plant size

Inventive Principle:
Principle #7Nested doll (Nesting)

2Productivity

If synthesis gas is produced in large quantities, then production capacity is met, but storage becomes difficult and risky due to carbon monoxide toxicity

Engineering Contradiction:
Improvesynthesis gas production capacityVSAvoidcarbon monoxide toxicity risk
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The invention extracts the catalytic function from traditional large-scale continuous production systems and concentrates it into compact modular reactors. By using structured catalysts with high surface area-to-volume ratio, the system achieves large production capacity in small footprints, eliminating the need for large storage facilities and reducing CO toxicity risks associated with storage

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The structured catalyst design enables continuous on-demand synthesis gas production directly at the point of use. The modular reactors can be operated continuously to meet production requirements without interrupting for storage management, eliminating the harmful storage phase and associated CO toxicity risks

Inventive Principle:
Principle #20Continuity of useful action

3Productivity

If endothermic reactions are used for synthesis gas production, then chemical conversion is achieved, but energy consumption increases

Engineering Contradiction:
Improvesynthesis gas production capacityVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent applies local quality by creating regions of high catalytic activity within the honeycomb cells where the catalytically active material is deposited. This localized catalysis occurs at specific sites (cell walls) rather than requiring bulk heating of entire large volumes, reducing overall energy consumption while maintaining high production capacity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The honeycomb structure provides high surface area porous walls within each cell for catalyst deposition. This porous architecture increases the effective catalytic surface area without increasing reactor volume, enabling efficient endothermic reactions with lower energy input requirements per unit of synthesis gas produced

Inventive Principle:
Principle #31Porous materials

4Adaptability or versatility

If modular macroscopic structures are used, then plant design flexibility increases, but manufacturing complexity increases

Engineering Contradiction:
Improveplant design flexibilityVSAvoidcatalyst manufacturing complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The catalyst is segmented into standardized modular macroscopic structures (honeycomb monoliths) with uniform cell geometries. These standardized modules can be manufactured using consistent processes and then assembled in various configurations to meet different production requirements, providing design flexibility without proportionally increasing manufacturing complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The modular macroscopic honeycomb structures serve multiple functions: they provide structural support, define flow channels, support catalytic material deposition, and enable scalable assembly. This multi-functionality reduces the number of separate manufacturing steps needed compared to traditional catalyst forms, balancing manufacturing complexity with design flexibility

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This setup allows compact, safe, and efficient synthesis gas production in decentralized plants, reducing the need for gas storage and handling risks, with high production capacity and flexible plant design.

Implementation Method 1

heat for the endothermic reaction is provided by resistance heating

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

the macroscopic structure supports a catalytically active material

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS12377410B2Structured catalyst
Publication Date: 2025.08.05 HALDOR TOPSOE AS
  • US12377410B2 patent drawing
  • US12377410B2 patent drawing
  • US12377410B2 patent drawing

AI summary

A structured catalyst for catalyzing an endothermic reaction of a feed gas to convert it to a product gas Including at least one macroscopic structure of an electrically conductive material and at least one connector attached to the at least one macroscopic structure, wherein the macroscopic structure supports a catalytically active material.