STT MRAM Free Layer Stack With Spacers for Low Switching Current

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Solution Overview

Problem

Existing STT MRAM devices face challenges in reducing the critical switching current density while maintaining thermal stability, due to the trade-offs in film thickness, damping constant, and saturation magnetization.

Innovation Solution

The STT magnetoresistive memory device incorporates a free layer stack with a total thickness of less than 2 nm, comprising a proximal ferromagnetic layer, non-magnetic metal sub-monolayers, an intermediate ferromagnetic layer, and a distal ferromagnetic layer, to minimize increases in damping and reduce saturation magnetization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If the free layer thickness is reduced to lower critical switching current density, then switching current density decreases, but thermal stability deteriorates

Engineering Contradiction:
Improvecritical switching current densityVSAvoidthermal stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The free layer is segmented into multiple thin ferromagnetic layers (first, second, and third ferromagnetic layers) separated by nonmagnetic metal spacers. This segmentation allows each layer to contribute to the overall magnetic moment while maintaining a total thickness less than 2 nm, achieving low switching current density. The segmented structure also enables independent optimization of each layer's properties to maintain thermal stability through enhanced perpendicular magnetic anisotropy at the interfaces.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs a composite structure combining ferromagnetic layers with nonmagnetic metal spacers (such as ruthenium, rhodium, or iridium). This composite architecture creates perpendicular magnetic anisotropy at the ferromagnetic/nonmagnetic interfaces, which enhances thermal stability while keeping the total free layer thickness minimal. The nonmagnetic spacers prevent magnetic coupling between ferromagnetic layers while contributing to the anisotropy effect.

Inventive Principle:
Principle #40Composite materials

2Reliability

If perpendicular magnetic anisotropy is enhanced by adding nonmagnetic metal layers, then thermal stability improves, but damping constant increases

Engineering Contradiction:
Improvethermal stabilityVSAvoiddamping constant
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The nonmagnetic metal spacers are strategically positioned only at specific interfaces within the free layer stack, creating localized perpendicular magnetic anisotropy where needed. The spacers are placed between ferromagnetic layers to generate interface anisotropy, while the bulk ferromagnetic layers maintain their original magnetic properties with lower damping. This localized approach enhances thermal stability without uniformly increasing damping across the entire free layer.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes the thickness and material composition of nonmagnetic metal spacers to achieve the desired perpendicular magnetic anisotropy while minimizing damping increases. By controlling the spacer thickness to be very thin (sub-nanometer scale) and selecting specific materials (Ru, Rh, Ir), the interface anisotropy is maximized while the negative impact on damping is minimized. The ferromagnetic layer compositions (CoFeB, CoFe) are also tuned to balance anisotropy and damping properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances perpendicular magnetic anisotropy without increasing damping or degrading magnetic moment, resulting in improved thermal stability and reduced switching current density.

Implementation Method 1

Spin-transfer torque (STT) refers to an effect in which the orientation of a magnetic layer in a magnetic tunnel junction or spin valve is modified by a spin-polarized current. When the spin-polarized current flows through a free layer of a magnetic tunnel junction or a spin valve, the electrons in the spin-polarized current can transfer at least some of their angular momentum to the free layer, thereby producing a torque on the magnetization of the free layer.

Methodology Applied
Scientific EffectSpin-transfer torque:

Implementation Method 2

A resistance differential of a magnetic tunnel junction between different magnetization states of the free layer can be employed to store data within the magnetoresistive random access memory (MRAM) cell depending if the magnetization of the free layer is parallel or antiparallel to the magnetization of the polarizer layer

Methodology Applied
Scientific EffectMagnetoresistance: Magnetoresistance

Implementation Method 3

enhances perpendicular magnetic anisotropy without increasing damping or degrading magnetic moment, resulting in improved thermal stability

Methodology Applied
Scientific EffectPerpendicular magnetic anisotropy: Anisotropy

Data Source

PatentUS12283296B2Spin-transfer torque magnetoresistive memory device with a free layer stack including multiple spacers and methods of making the same
Publication Date: 2025.04.22 SANDISK TECHNOLOGIES LLC
  • US12283296B2 patent drawing
  • US12283296B2 patent drawing
  • US12283296B2 patent drawing

AI summary

A spin-transfer torque (STT) magnetoresistive memory device includes a first electrode, a second electrode, and a magnetic tunnel junction located between the first electrode and the second electrode. The magnetic tunnel junction includes a reference layer having a fixed magnetization direction, a free layer stack, and a nonmagnetic tunnel barrier layer located between the reference layer and the free layer stack. The free layer stack has a total thickness of less than 2 nm, and contains in order, a proximal ferromagnetic layer located proximal to the nonmagnetic tunnel barrier layer, a first non-magnetic metal sub-monolayer, an intermediate ferromagnetic layer, a second non-magnetic metal sub-monolayer, and a distal ferromagnetic layer.