Perpendicular STTM Device Conductive Oxide Layer Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Perpendicular spin transfer torque memory (STTM) devices face challenges in stability as they scale down, requiring enhanced methods to maintain performance and distinguish between '1' and '0' states effectively.

Innovation Solution

Incorporating a conductive oxide layer adjacent the free magnetic layer, which oxidizes iron/cobalt atoms, providing additional stability without increasing resistance, and using a multi-layer electrode structure with alternating magnetic and non-magnetic layers to enhance perpendicular spin dominance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conductive oxide layer is added adjacent to the free magnetic layer, then coercivity and stability are enhanced, but device structure and fabrication complexity increase

Engineering Contradiction:
Improvecoercivity stabilityVSAvoidmulti-layer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A conductive oxide layer is introduced as an intermediary between the free magnetic layer and the electrode. This oxide layer serves as a mediator that oxidizes iron/cobalt atoms at the interface, thereby enhancing perpendicular spin dominance and coercivity stability without significantly increasing resistance or device complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The device employs a composite structure combining magnetic layers (CoFeB, CoFe), dielectric layers (MgO), and conductive oxide layers. This composite material approach allows the conductive oxide to provide both electrical conductivity and chemical reactivity for oxidizing metal atoms, achieving enhanced stability through material composition rather than structural complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If the free magnetic layer is made thinner to improve scaling, then device density increases, but stability and coercivity decrease

Engineering Contradiction:
Improvedevice scaling densityVSAvoidcoercivity stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes the chemical state of iron/cobalt atoms at the interface by introducing oxygen through the conductive oxide layer. This parameter change (oxidation state) fundamentally alters the magnetic anisotropy, providing enhanced perpendicular spin dominance that compensates for the reduced thickness of the free magnetic layer, thereby maintaining stability during scaling

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The conductive oxide layer creates a localized region of oxidized iron/cobalt atoms specifically at the interface between the free magnetic layer and the electrode. This local oxidation enhances perpendicular magnetization precisely where needed, allowing the bulk of the free magnetic layer to remain thin for scaling while maintaining overall device stability

Inventive Principle:
Principle #3Local quality

3Measurement precision

If alternating magnetic and non-magnetic layers are added to enhance perpendicular spin dominance, then spin state detection improves, but manufacturing steps and process complexity increase

Engineering Contradiction:
Improvespin state detection precisionVSAvoidfabrication process simplicity
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The free magnetic layer is segmented into alternating magnetic (CoFeB, CoFe) and non-magnetic (Ru, Ta) layers. This segmentation creates multiple interfaces that collectively enhance perpendicular spin dominance, improving spin state detection precision through cumulative interface effects while using standard thin-film deposition techniques

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The alternating layer structure changes the magnetic parameters through interface effects, where each magnetic/non-magnetic interface contributes to perpendicular anisotropy. This parameter enhancement improves spin state detection without requiring complex fabrication processes, as the layers can be deposited using conventional sputtering or MBE techniques

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The conductive oxide layer significantly enhances coercivity by 3-4 fold, maintaining low resistance and improving the ability to detect spin states, thus improving the stability and performance of perpendicular STTM devices.

Implementation Method 1

Incorporating a conductive oxide layer adjacent the free magnetic layer, which oxidizes iron/cobalt atoms, providing additional stability

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

The operation of spin torque devices is based on the phenomenon of spin transfer torque. If a current is passed through a magnetization layer, called the fixed magnetic layer, it will come out spin polarized. With the passing of each electron, its spin (angular momentum) will be transferred to the magnetization in the next magnetic layer, called the free magnetic layer, and will cause a small change on its magnetization.

Methodology Applied
Scientific EffectSpin transfer torque:

Data Source

PatentUS9882123B2Perpendicular spin transfer torque memory (STTM) device with enhanced stability and method to form same
Publication Date: 2018.01.30 SAMSUNG ELECTRONICS CO LTD
  • US9882123B2 patent drawing
  • US9882123B2 patent drawing
  • US9882123B2 patent drawing

AI summary

Perpendicular spin transfer torque memory (STTM) devices with enhanced stability and methods of fabricating perpendicular STTM devices with enhanced stability are described. For example, a material layer stack for a magnetic tunneling junction includes a fixed magnetic layer. A dielectric layer is disposed above the fixed magnetic layer. A free magnetic layer is disposed above the dielectric layer. A conductive oxide material layer is disposed on the free magnetic layer.