Styphnate Salt Primer Composition for High-Temperature Engine Use

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Solution Overview

Problem

Conventional primer compositions used in motor vehicle safety systems and ammunition have low decomposition temperatures, making them unsuitable for engine compartments where temperatures exceed 140°C, and often contain heavy metals, limiting their application in mechanical and electrical systems.

Innovation Solution

Development of a primer composition utilizing alkali and alkaline-earth salts of styphnic acid, specifically potassium styphnate, calcium styphnate, and their mixed salts, which have a decomposition temperature above 300°C and are free of heavy metals, allowing for use in both mechanical and electrical primer systems, including engine compartments, by incorporating additives such as oxidizing agents, reducing agents, and binders.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional primer substances are used, then the primer composition can be easily manufactured and applied, but the decomposition temperature is too low (below 300°C) for use in engine compartments

Engineering Contradiction:
Improvedecomposition temperatureVSAvoidmanufacturing complexity
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters by using alkali and alkaline-earth metal salts of styphnic acid instead of conventional organic azides or lead compounds. This parameter change raises the decomposition temperature above 300°C while maintaining manufacturability through established chemical synthesis routes for styphnate salts.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If conventional primer substances are used, then the primer composition can be easily applied, but it contains heavy metals making it unsuitable for certain applications

Engineering Contradiction:
Improveheavy metal contentVSAvoidapplication range
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent extracts and eliminates heavy metals (particularly lead) from the primer composition by replacing conventional primer substances with heavy metal-free alkali and alkaline-earth metal styphnates. This extraction of harmful substances expands the application range to include engine compartments and environmentally sensitive applications while maintaining ease of application.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If a primer substance with high decomposition temperature is used, then it can withstand engine compartment temperatures, but it requires complex production processes

Engineering Contradiction:
Improvethermal stabilityVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs composite material strategies by formulating primer compositions that combine styphnate salts with complementary additives and binders. This composite approach achieves the required thermal stability above 300°C through synergistic material combinations while utilizing conventional primer formulation and manufacturing processes, avoiding excessive production complexity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The primer composition achieves high thermal stability, can be ignited both mechanically and electrically, and forms calcium carbonate residues with advantageous tribological properties, enabling safe and effective use in motor vehicle safety systems and ammunition without heavy metal contamination.

Implementation Method 1

the decomposition temperature of the primer composition according to the invention is above 300° C.

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

comprises one or more additives selected from: oxidising agents, reducing agents, sensitisers, binders, high-energy additives, combustion moderators and/or processing aids

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 3

when calcium styphnate and potassium-calcium styphnate are used as primer substance, by its calcium content, which by formation of calcium carbonate in the combustion residues is advantageous for weapons systems

Methodology Applied
Scientific EffectChemical transformation: Chemical Bonding

Data Source

PatentUS9663413B2Primer composition
Publication Date: 2017.05.30 RWS GMBH

AI summary

The invention relates to a primer composition, to a method for producing the same and to the use of said primer composition.