Subsea Flexible Pipe Sacrificial Layer for Armor Corrosion Control

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Solution Overview

Problem

Flexible pipes used in subsea hydrocarbon transport face significant mechanical stress and corrosion issues due to high tensile armor loads and exposure to corrosive gases like hydrogen sulfide and carbon dioxide, leading to potential loss of mechanical integrity and stress corrosion cracking.

Innovation Solution

Incorporation of a sacrificial metal layer with a porous body, such as metal foam or wool, impregnated with a water-soluble resin, which reacts with oxygen and consumes hydrogen sulfide, reducing corrosion and enhancing mechanical strength by providing additional surface area for reaction and cathodic protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If metallic tensile armor layers are used to ensure good tensile strength, then mechanical strength is improved, but corrosion resistance deteriorates due to exposure to corrosive gases and water in the annular space

Engineering Contradiction:
Improvetensile strengthVSAvoidcorrosion resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

A sacrificial metal layer is introduced as an intermediary between the corrosive environment (corrosive gases and water in the annular space) and the metallic tensile armor layers. This sacrificial layer preferentially corrodes, protecting the tensile armor from direct exposure to corrosive agents, thereby maintaining both mechanical strength and corrosion resistance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The sacrificial metal layer is designed to be consumed over time as it corrodes preferentially, protecting the more valuable tensile armor layers. This disposable layer sacrifices itself to extend the service life of the entire pipe structure, particularly protecting the load-bearing components.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Length of moving object

If the line length is increased to serve greater depths, then service capability is improved, but mechanical stress on tensile armor increases leading to higher corrosion risk

Engineering Contradiction:
Improveline lengthVSAvoidmechanical stress and corrosion
Core Design Contradiction:
Length of moving objectVSObject-affected harmful factors

Solution Approach 1:

The sacrificial metal layer serves as a protective intermediary that becomes increasingly important as line length increases. It absorbs the corrosive effects that would otherwise accumulate and intensify over the extended length of the pipe, particularly protecting the tensile armor from stress corrosion cracking in the annular space.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The sacrificial layer provides beforehand cushioning against corrosion by being positioned in advance to intercept corrosive agents before they can reach the tensile armor. This pre-protective measure is particularly valuable in long lines where cumulative exposure to corrosive environments would be severe.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sacrificial layer effectively limits corrosion and enhances the mechanical strength and service life of the flexible pipe by rapidly reacting with oxygen and reducing hydrogen sulfide concentrations, thereby preventing stress corrosion cracking and extending the pipe's operational lifespan.

Implementation Method 1

a first sacrificial layer (18) made from a porous body (30) at least partially metallic... which reacts with oxygen

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

reacts with oxygen and consumes hydrogen sulfide, reducing corrosion

Methodology Applied
Scientific EffectChemical reduction: Reduction

Implementation Method 3

a porous body (30) at least partially metallic... providing additional surface area for reaction

Methodology Applied
Scientific EffectPorosity: Porosity

Data Source

PatentEP3768506B1Line to be submerged in a body of water, and associated production method
Publication Date: 2022.01.19 TECH N POWER
  • EP3768506B1 patent drawingFigure 1~2
  • EP3768506B1 patent drawingFigure 3~4
  • EP3768506B1 patent drawingFigure 5

AI summary

The invention relates to a line to be submerged in a body of water, comprising: an outer sheath defining an inner volume; an inner sheath arranged in the inner volume and defining a passage for the transport of a fluid, particularly of hydrocarbons, the inner sheath and the outer sheath together defining an annular space; and at least one traction armour ply arranged in the annular space. The line comprises at least one metal sacrificial layer (18) arranged in the annular space, the sacrificial layer (18) comprising a porous body (30) having a minimum specific surface area of at least 5 cm2/g, and the sacrificial layer (18) having a linear metal surface per metre of line of at least 0.3 m2/m.