Substrate Cleaning via Partial Etching to Expose Embedded Particles

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Solution Overview

Problem

Fine patterns on substrates are prone to damage during physical cleaning, limiting the range of physical force that can be applied for effective particle removal without causing pattern damage, resulting in a narrow process window that makes it difficult to achieve both efficient particle removal and pattern protection.

Innovation Solution

A substrate cleaning method involving partial etching of the oxide film to expose particles, followed by physical cleaning with reduced energy, using techniques like two-fluid cleaning, ultrasonic cleaning, or inkjet cleaning, to remove particles while minimizing pattern damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If physical cleaning with high kinetic energy is applied to remove particles, then particle removal performance is improved, but pattern damage occurs

Engineering Contradiction:
Improveparticle removal performanceVSAvoidpattern damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The oxide film is partially etched before physical cleaning to expose particles embedded within it. This preliminary action makes particles more accessible to the cleaning fluid, allowing effective removal with lower kinetic energy and thus preventing pattern damage while maintaining particle removal performance

Inventive Principle:
Principle #10Preliminary action

2Productivity

If physical force is increased to remove particles embedded in oxide film, then particle removal performance is improved, but the process window becomes narrower

Engineering Contradiction:
Improveparticle removal performanceVSAvoidprocess window
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

Partial etching of the oxide film is performed before physical cleaning to expose particles. This preliminary action expands the process window by enabling effective particle removal with a broader range of physical cleaning conditions, as particles are no longer buried deep within the oxide film

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The etching is applied selectively to the oxide film regions containing particles, rather than uniformly removing the entire oxide film. This localized approach maintains the oxide film's protective function while exposing particles for removal, thereby widening the acceptable process window

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method allows for efficient particle removal with reduced energy, effectively widening the process window and preventing pattern damage by selectively exposing particles through partial etching and using controlled physical cleaning methods.

Implementation Method 1

a partial etching step of etching the oxide film to a predetermined film thickness

Methodology Applied
Scientific EffectEtching: Ablation

Implementation Method 2

Droplets in the mixed fluid collide with the surface of the substrate, and the impact causes particles on the surface of the substrate to be separated and thereby removed from the substrate

Methodology Applied
Scientific EffectKinetic energy impact: Impact Force

Implementation Method 3

Specific examples of physical cleaning include ultrasonic cleaning

Methodology Applied
Scientific EffectUltrasonic cleaning: Ultrasonic Vibration

Data Source

PatentUS10840083B2Substrate cleaning method, method for creating substrate cleaning recipe, and device for creating substrate cleaning recipe
Publication Date: 2020.11.17 SCREEN HOLDINGS CO LTD
  • US10840083B2 patent drawing
  • US10840083B2 patent drawing
  • US10840083B2 patent drawing

AI summary

Provided is a substrate cleaning method for cleaning a substrate having an oxide film on the surface thereof. The method includes a partial etching step of etching the oxide film to a predetermined film thickness, and a physical cleaning step of executing physical cleaning on the surface of the substrate after the partial etching step. The oxide film may be a natural oxide film with particles at least partially taken into the film. In this case, the partial etching step may either expose the particles from the natural oxide film or increase the exposed portion from the natural oxide film. The physical cleaning may remove, by physical action, the particles exposed from the natural oxide film while leaving the natural oxide film on the surface of the substrate.