Substrate Film Deposition Cycles for High Step Coverage Filling

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Solution Overview

Problem

The challenge of achieving high step coverage and high filling characteristics in film formation during the miniaturization and complication of device geometries in LSI manufacturing processes is not adequately addressed by existing technologies.

Innovation Solution

A substrate processing method involving a cycle of sequentially supplying a first modifying gas, a precursor gas, a second modifying gas, and a reaction gas, with specific control of gas partial pressures and flow rates to enhance film uniformity and filling characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional film formation methods are used, then the manufacturing process is simple, but the film thickness uniformity and filling characteristics are insufficient for miniaturized device geometries

Engineering Contradiction:
Improvefilm thickness uniformityVSAvoidgas supply sequence complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The film formation process is segmented into multiple sequential gas supply steps: (a) supplying a first modifying gas, (b) supplying a precursor gas, (c) supplying a second modifying gas, and (d) supplying a reaction gas. This segmentation allows precise control over film deposition at different stages, improving thickness uniformity and filling characteristics in miniaturized structures.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs periodic cycling through the four gas supply steps (a)-(d) repeatedly during film formation. This periodic action enables controlled deposition cycles that enhance film uniformity and filling characteristics by repeatedly modifying and depositing material in a controlled sequence.

Inventive Principle:
Principle #19Periodic action

2Manufacturing precision

If conventional film formation methods are used, then the process time is short, but the filling characteristics and step coverage are insufficient

Engineering Contradiction:
Improvefilling characteristicsVSAvoidfilm formation cycle time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The first modifying gas is supplied in advance (before precursor gas) to pre-condition the substrate surface and enhance gas distribution into recessed structures. This preliminary action improves filling characteristics by ensuring better precursor gas penetration into deep trenches and vias before the actual deposition begins.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes multiple process parameters including gas flow rates, partial pressures, and supply timing for each of the four gases. By optimizing these parameters, the process achieves superior filling characteristics while managing the extended cycle time through efficient parameter coordination.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If high film thickness uniformity is achieved through multiple gas supply steps, then the film quality improves, but the process complexity increases

Engineering Contradiction:
Improvefilm qualityVSAvoidprocess implementation difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The modifying gases (first and second) act as intermediaries between the precursor gas and the final film structure. These intermediary gases facilitate controlled surface modification and reaction conditions, enabling high film quality through gradual, controlled transformations rather than direct deposition.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The film formation process creates a composite structure through sequential deposition of materials from different gas sources. The first modifying gas, precursor gas, second modifying gas, and reaction gas each contribute different components or modifications, creating a composite film structure with enhanced properties and uniformity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method improves film thickness uniformity and filling characteristics, reducing impurities and voids, and enhances the electrical characteristics of the film.

Implementation Method 1

supplying a first modifying gas, which is an inorganic halogen element-containing gas

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

supplying a reaction gas

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

supplying a precursor gas

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS20250215564A1Method of processing substrate, method of manufacturing semiconductor device, substrate processing apparatus, and recording medium
Publication Date: 2025.07.03 KOKUSAI DENKI KK
  • US20250215564A1 patent drawing
  • US20250215564A1 patent drawing
  • US20250215564A1 patent drawing

AI summary

There is provided a technique that includes: performing a cycle a predetermined number of times on the substrate, the cycle including sequentially performing: (a) supplying a first modifying gas, which is an inorganic halogen element-containing gas; (b) supplying a precursor gas; (c) supplying a second modifying gas, which is an inorganic halogen element-containing gas; and (d) supplying a reaction gas.