Substrate Drying via Shear Force to Prevent Pattern Collapse

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Solution Overview

Problem

Conventional sublimation drying methods for substrates result in pattern collapse due to uneven film formation caused by the low viscosity and film formability issues of sublimation materials, leading to deformation of surface patterns.

Innovation Solution

A substrate processing method that involves applying a sublimation material dissolved in a volatile solvent, changing the rotation acceleration to apply a shear force and eliminate association states, thereby reducing film formation unevenness and preventing pattern collapse.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional sublimation drying is used with low viscosity sublimation material, then drying capability is achieved, but film formation unevenness occurs causing pattern collapse

Engineering Contradiction:
Improvedrying capabilityVSAvoidfilm formation uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the physical-chemical parameters of the sublimation material by selecting specific compounds with appropriate molecular weight ranges (100-300) and controlling solution concentration (1-10 wt%), transforming the material properties to achieve both good film formation and sublimation drying performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies different properties to different aspects of the sublimation material: the molecular weight and chemical structure are optimized for film formation uniformity, while the sublimation point and volatility are optimized for drying capability, achieving local optimization of material properties

Inventive Principle:
Principle #3Local quality

2Reliability

If low molecular organic material is used as sublimation material, then sublimation drying function is achieved, but film formability deteriorates due to low viscosity

Engineering Contradiction:
Improvesublimation drying functionVSAvoidfilm formability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention optimizes the molecular weight parameter to a specific range (100-300) and controls the solution concentration (1-10 wt%), transforming the material from having poor film formability to achieving uniform film deposition while maintaining sublimation drying function

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite system by dissolving the sublimation material in a specific solvent to form a solution with optimized viscosity and film-forming properties, combining the advantages of both the sublimation material and the solvent

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively suppresses film formation unevenness and pattern deformation by eliminating association states of the sublimation material, ensuring a smoother and more uniform film deposition during the drying process.

Implementation Method 1

The precipitated sublimation material is changed from a solid phase to a gas phase (sublimation), so that the sublimation material is removed from the surface of the substrate.

Methodology Applied
Scientific EffectSublimation: Sublimation

Implementation Method 2

a solution in which a low molecular organic material is dissolved in a highly volatile solvent, as a sublimation material containing liquid

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

changing the rotation acceleration to apply a shear force and eliminate association states

Methodology Applied
Scientific EffectShear force: Shear Stress

Data Source

PatentUS10304704B2Substrate processing method and substrate processing apparatus
Publication Date: 2019.05.28 KIOXIA CORP
  • US10304704B2 patent drawing
  • US10304704B2 patent drawing
  • US10304704B2 patent drawing

AI summary

A substrate processing method according to an embodiment is a substrate processing method for drying a substrate. The substrate processing method includes supplying a solution in which a sublimation material is dissolved in a first solvent to a surface of a cleaned substrate. The substrate processing method includes eliminating at least a portion of association states of the sublimation material. The substrate processing method includes precipitating the sublimation material on the surface of the substrate. The substrate processing method includes removing the precipitated sublimation material by sublimation.