Substrate Drying Apparatus Using Supercritical Fluids

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Solution Overview

Problem

Conventional drying processes for semiconductor substrates with fine circuit patterns are inefficient and prone to pattern damage, especially when the line width is less than 30 nm, due to low efficiency and pattern collapse during the drying process.

Innovation Solution

A substrate drying apparatus utilizing supercritical fluids with different temperatures and pressures to effectively dry the substrate, preventing pattern collapse and reducing particle generation by using a chamber, reservoirs, and a supply unit to manage the supercritical fluids, which are heated to specific temperatures and pressures to maintain their supercritical state.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional drying process using isopropyl alcohol is used, then substrate can be dried, but drying efficiency is low and pattern collapse occurs

Engineering Contradiction:
Improvedrying efficiencyVSAvoidpattern integrity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the physical parameters of the drying medium by using supercritical fluids instead of conventional isopropyl alcohol. The supercritical fluid is maintained at specific temperature and pressure conditions (temperature at or above critical point, pressure at or above critical pressure) to achieve both high drying efficiency and pattern integrity through its unique properties of high diffusivity and low surface tension

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transition of the drying medium by employing supercritical fluid that can transition between liquid-like and gas-like states. The supercritical fluid penetrates the substrate effectively and then transitions to gas phase for removal, enabling efficient drying without causing pattern collapse due to controlled phase change behavior

Inventive Principle:
Principle #36Phase transitions

2Productivity

If drying process is performed on substrate with fine circuit patterns, then substrate can be dried, but pattern damage frequently occurs

Engineering Contradiction:
Improvedrying capabilityVSAvoidpattern stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the physical parameters of the drying medium to supercritical state with temperature at or above critical point and pressure at or above critical pressure. This parameter change gives the drying medium high diffusivity for effective penetration and low surface tension to avoid pattern damage, simultaneously achieving drying capability and pattern stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional mechanical drying process (using liquid isopropyl alcohol and physical removal) with a supercritical fluid-based process. The supercritical fluid's unique properties eliminate the need for harsh mechanical drying actions that cause pattern collapse, providing both drying capability and pattern stability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Loss of time

If supercritical fluid with temperature less than substrate temperature is used, then drying time is reduced, but particle generation may increase

Engineering Contradiction:
Improvedrying timeVSAvoidparticle generation
Core Design Contradiction:
Loss of timeVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the temperature parameter of the supercritical fluid to be at or above its critical point but controlled relative to substrate temperature. This parameter optimization enables rapid drying by reducing temperature difference-driven convection time while maintaining supercritical properties that prevent particle generation through controlled fluid behavior

Inventive Principle:
Principle #35Parameter changes

4Productivity

If supercritical fluid with temperature greater than substrate temperature is used, then drying efficiency is improved, but particle generation increases

Engineering Contradiction:
Improvedrying efficiencyVSAvoidparticle generation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the temperature parameter of the supercritical fluid to be at or above its critical point, balancing drying efficiency with particle generation control. The supercritical state provides high diffusivity for efficient drying while the controlled temperature and pressure prevent excessive particle formation through managed fluid expansion and condensation behavior

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The apparatus reduces substrate drying time and decreases particle generation, ensuring efficient drying of semiconductor substrates without damaging fine patterns by using supercritical fluids that replace solvents and remove impurities effectively.

Implementation Method 1

A substrate drying apparatus utilizing supercritical fluids with different temperatures and pressures to effectively dry the substrate, preventing pattern collapse and reducing particle generation

Methodology Applied
Scientific EffectSupercritical fluid extraction: Supercritical Fluid Extraction

Implementation Method 2

heated to specific temperatures and pressures to maintain their supercritical state

Methodology Applied
Scientific EffectPhase transition: Phase Change

Data Source

PatentUS10825698B2Substrate drying apparatus, facility of manufacturing semiconductor device, and method of drying substrate
Publication Date: 2020.11.03 SAMSUNG ELECTRONICS CO LTD
  • US10825698B2 patent drawing
  • US10825698B2 patent drawing
  • US10825698B2 patent drawing

AI summary

Disclosed are a substrate drying apparatus, a facility of manufacturing a semiconductor device, and a method of drying a substrate. The substrate drying apparatus includes a chamber that is configured to dry a substrate at a first temperature, a first reservoir that is configured to store a first supercritical fluid at a second temperature that is less than the first temperature, a second reservoir that is configured to store a second supercritical fluid at a third temperature that is greater than the first temperature, and a supply unit connected between the chamber and the first reservoir and/or second reservoir. The supply unit is configured to supply the chamber with the first supercritical fluid and second supercritical fluid.