Substrate Film Deposition Sequence for 3D Step Coverage

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Solution Overview

Problem

Existing methods face challenges in achieving optimal step coverage of films formed on substrates with complex three-dimensional structures, such as trenches and grooves, during semiconductor device manufacturing.

Innovation Solution

A method involving a cycle of supplying an inhibitor, a first precursor, a second precursor, and a reactant to the substrate, with each step optimized to enhance film formation on both the surface and inner recesses of the substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a conventional film formation process is used, then the film can be formed on the substrate surface, but the step coverage on complex three-dimensional structures (trenches and grooves) is insufficient

Engineering Contradiction:
Improvestep coverageVSAvoidsubstrate structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The film formation process is segmented into multiple sequential steps: inhibitor supply step, first precursor supply step, second precursor supply step, and reactant supply step. Each step targets different regions of the substrate structure, with the inhibitor preferentially adsorbing on horizontal surfaces and the precursors filling vertical trenches and grooves, thereby achieving uniform step coverage on complex three-dimensional structures

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The inhibitor is supplied in advance before the precursors to pre-adsorb on the substrate surface, particularly on horizontal surfaces. This preliminary action prevents unwanted precursor adsorption on horizontal surfaces while allowing precursors to penetrate and adsorb on vertical sidewalls of trenches and grooves, improving step coverage before the actual film formation begins

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves the step coverage of films on substrates with complex structures by preferentially adsorbing and forming layers on both the surface and inner recesses, enhancing the manufacturing process efficiency.

Implementation Method 1

an inhibitor is supplied to a substrate; a first precursor is supplied from a first reservoir to the substrate

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a first precursor is supplied from a first reservoir to the substrate; a second precursor is supplied from a second reservoir to the substrate

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 3

a reactant is supplied to the substrate

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentEP4650483A1Method of processing substrate, method of manufacturing semiconductor device, program, and substrate processing apparatus
Publication Date: 2025.11.19 KOKUSAI DENKI KK
  • EP4650483A1 patent drawingFigure 1
  • EP4650483A1 patent drawingFigure 2
  • EP4650483A1 patent drawingFigure 3

AI summary

There is provided a technique that includes forming a film on a substrate (200) by performing a cycle a predetermined number of times, the cycle including: (a) supplying an inhibitor to the substrate (200); (b) supplying a first precursor from a first reservoir (240a) to the substrate (200); (c) supplying a second precursor from a second reservoir (240b) to the substrate (200); and (d) supplying a reactant to the substrate (200).