Substrate Film Deposition with Regulated Adsorption Control

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Solution Overview

Problem

Existing substrate processing methods for semiconductor devices face challenges in improving the characteristics of films formed on substrates, particularly in controlling the adsorption of precursor and reactant molecules, which affects film quality and efficiency.

Innovation Solution

A method involving the sequential and overlapping supply of a precursor, reactant, and a regulating agent to the substrate, with precise control of exposure amounts and conditions to manage adsorption, including the use of halogen-containing agents and alkyl groups to inhibit precursor adsorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a precursor and reactant are supplied to a substrate to form a film, then film formation is achieved, but the characteristics of the formed film are insufficient

Engineering Contradiction:
Improvefilm characteristicsVSAvoidfilm formation efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The film formation process is divided into multiple discrete steps: precursor supply, regulating agent supply, reactant supply, and overlapping supply phases. This segmentation allows precise control of each stage to optimize both film characteristics and formation efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The regulating agent is supplied before the reactant to pre-regulate the adsorption state of the substrate surface. This preliminary action controls the amount of precursor and reactant that will be adsorbed, ensuring optimal film characteristics from the outset

Inventive Principle:
Principle #10Preliminary action

Solution Approach 3:

The method dynamically adjusts the supply timing and overlap of precursor, regulating agent, and reactant. By controlling the overlapping periods where multiple gases are supplied simultaneously, the process adapts to achieve desired film properties while maintaining efficiency

Inventive Principle:
Principle #15Dynamics

2Manufacturing precision

If the amount of precursor and reactant adsorbed on the substrate is increased to improve film quality, then film characteristics improve, but adsorption control becomes difficult

Engineering Contradiction:
Improvefilm qualityVSAvoidadsorption control complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

A regulating agent is introduced as an intermediary substance that mediates between the precursor/reactant and the substrate surface. This agent controls the adsorption process by regulating the amount of precursor and reactant that can be adsorbed, simplifying the control mechanism while improving film quality

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The method changes the chemical environment by introducing the regulating agent, which alters the adsorption parameters of the substrate surface. This parameter change enables precise control over the amount of precursor and reactant adsorbed, directly impacting film quality

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances film formation by regulating adsorption, leading to improved film quality and efficiency in semiconductor device manufacturing.

Implementation Method 1

supplying a regulating agent, which regulates an amount of at least one selected from the group of a molecule of the precursor and a molecule of the reactant adsorbed on the substrate, to the substrate

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20260018408A1Method of processing substrate, method of manufacturing semiconductor device, recording medium, and substrate processing apparatus
Publication Date: 2026.01.15 KOKUSAI DENKI KK
  • US20260018408A1 patent drawing
  • US20260018408A1 patent drawing
  • US20260018408A1 patent drawing

AI summary

There is provided a technique that includes: (a) supplying a precursor to a substrate; (b) supplying a reactant to the substrate; (c) supplying a regulating agent, which regulates an amount of at least one selected from the group of a molecule of the precursor and a molecule of the reactant adsorbed on the substrate, to the substrate; (d) performing a process in which at least one selected from the group of (a) and (b) overlaps (c); and (e) after (d), performing (a) or (b) which overlaps (c) in (d), independently of (c).