Substrate Film Processing for Precise Air Gap Formation

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Solution Overview

Problem

The challenge in semiconductor manufacturing is to precisely form an air gap on a substrate with high accuracy as devices miniaturize.

Innovation Solution

A method involving the formation of a third film on a first and second film on a substrate by supplying precursors and reactants under conditions where physical adsorption dominates, followed by etching to remove the first film while retaining the second and third films.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional plasma-based methods are used to form air gaps, then the air gap can be formed, but plasma damage occurs and manufacturing precision decreases

Engineering Contradiction:
Improveair gap formation accuracyVSAvoidplasma damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the fundamental parameter of the processing atmosphere from plasma state to non-plasma state. By performing film formation and etching steps in a non-plasma atmosphere, the method eliminates plasma damage to the substrate while maintaining high precision air gap formation through controlled chemical reactions and physical adsorption processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a non-plasma inert atmosphere environment for the film formation and etching processes. This inert environment protects the substrate from plasma-induced damage while still enabling the necessary chemical reactions to proceed through alternative mechanisms such as controlled chemical vapor deposition and selective etching with etching agents

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Manufacturing precision

If multiple process steps are used to form air gaps with high precision, then manufacturing precision improves, but device complexity and processing time increase

Engineering Contradiction:
Improveair gap formation accuracyVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges multiple process steps into a more integrated sequence. By forming the third film under specific conditions where physical adsorption dominates, and then using a single etching step with appropriate etching agents to remove the first film while retaining the second and third films, the method achieves high precision air gap formation with reduced process complexity compared to conventional multi-step plasma processes

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent performs preliminary film formation steps under controlled conditions where physical adsorption dominates before the etching step. This preliminary action of forming the third film with specific adsorption characteristics prepares the structure for selective etching, enabling high precision air gap formation while simplifying the overall process by establishing clear differentiation between removable and retained films beforehand

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables precise formation of an air gap with high accuracy, simplifies the process, enhances productivity, and reduces plasma damage by performing steps in a non-plasma atmosphere.

Implementation Method 1

physical adsorption of the precursor occurs more predominantly than chemical adsorption of the precursor

Methodology Applied
Scientific EffectPhysical adsorption: Physisorption

Implementation Method 2

exposing the surface of the substrate where the third film is formed on the first film and the second film to an etching agent that reacts with the first film

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS20250226206A1Method of processing substrate, method of manufacturing semiconductor device, substrate processing system, and recording medium
Publication Date: 2025.07.10 KOKUSAI DENKI KK
  • US20250226206A1 patent drawing
  • US20250226206A1 patent drawing
  • US20250226206A1 patent drawing

AI summary

There is provided a technique that includes: (a) forming a third film on a first film and a second film formed on a surface of the substrate by supplying a precursor, a first reactant, and a second reactant to the substrate under a condition in which thermal decomposition of the precursor does not occur and physical adsorption of the precursor occurs more predominantly than chemical adsorption of the precursor when the precursor is present alone; and (b) removing the first film while retaining the second film and the third film by exposing the surface of the substrate where the third film is formed on the first film and the second film to an etching agent that reacts with the first film.