Substrate Pre-Coating Sequence for Stable Semiconductor Film Thickness

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Solution Overview

Problem

The existing substrate processing apparatuses face challenges in reducing downtime and improving productivity due to prolonged pre-coating times and film thickness drop phenomena during the manufacturing of semiconductor devices.

Innovation Solution

A technique involving the formation of a SiON film as a first pre-coated film and a SiOCN film as a second pre-coated film in the process container, with specific gas supply sequences and thickness settings, to shorten pre-coating time and downtime, while maintaining film quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-layer pre-coated film is formed in the process container, then the pre-coating process is simple, but the pre-coating time is prolonged and film thickness drop occurs

Engineering Contradiction:
Improvepre-coating process complexityVSAvoidpre-coating time
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The pre-coated film is divided into two distinct layers: a first pre-coated film formed from a nitrogen-containing processing gas, and a second pre-coated film formed from a carbon-containing processing gas. This segmentation allows each layer to perform specific functions, reducing overall pre-coating time while preventing film thickness drop during substrate processing.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The pre-coating structure uses a composite of two different materials with distinct chemical compositions and properties. The first layer (nitrogen-containing) and second layer (carbon-containing) work together to provide both time reduction and film thickness stability, achieving what a single homogeneous layer cannot accomplish.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If a thick pre-coated film is formed to prevent film thickness drop, then film quality is maintained, but pre-coating time increases

Engineering Contradiction:
Improvefilm thickness uniformityVSAvoidpre-coating time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

Instead of forming one thick pre-coated film, the structure segments the total thickness into two thinner layers with different materials. The first nitrogen-containing layer and second carbon-containing layer together provide sufficient coverage to prevent film thickness drop, but each layer is thin enough to form quickly, reducing total pre-coating time.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the chemical composition parameter of the pre-coated film by using two different materials (nitrogen-containing and carbon-containing) instead of a single material. This parameter change allows the pre-coating to achieve both speed and effectiveness, preventing film thickness drop without requiring excessive thickness.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional single-gas pre-coating is used, then the process is simple, but downtime of the substrate processing apparatus is prolonged

Engineering Contradiction:
Improvegas supply sequenceVSAvoidapparatus downtime
Core Design Contradiction:
Device complexityVSLoss of time

Solution Approach 1:

The pre-coating process is segmented into two sequential gas supply steps: first supplying a nitrogen-containing processing gas to form the first pre-coated film, then supplying a carbon-containing processing gas to form the second pre-coated film. This segmented approach reduces total pre-coating time and apparatus downtime compared to conventional single-gas methods.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The two-gas pre-coating process maintains continuous useful action by sequentially forming both pre-coated films without interrupting the pre-coating objective. The first gas layer is formed, then immediately followed by the second gas layer, creating a continuous process that minimizes downtime while achieving the dual benefit of time reduction and film thickness stability.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces pre-coating time by up to 60% and downtime, stabilizes film composition, and prevents film thickness drop and particle generation, enhancing the operating rate and quality of the substrate processing apparatus.

Implementation Method 1

forming a film on a substrate by supplying a first processing gas to the substrate in a process container

Methodology Applied
Scientific EffectChemical Vapor Deposition: Chemical Vapour Deposition

Implementation Method 2

forming a first pre-coated film, which has a first thickness and has a material different from a material of the film formed in (a), in the process container by supplying a second processing gas into the process container

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

forming a second pre-coated film, which has a second thickness smaller than the first thickness and has the same material as the material of the film formed in (a), on the first pre-coated film formed in the process container by supplying a third processing gas into the process container

Methodology Applied
Scientific EffectChemical Vapor Deposition: Chemical Vapour Deposition

Data Source

PatentUS11885016B2Method of processing substrate, method of manufacturing semiconductor device, substrate processing apparatus and recording medium
Publication Date: 2024.01.30 KOKUSAI DENKI KK
  • US11885016B2 patent drawing
  • US11885016B2 patent drawing
  • US11885016B2 patent drawing

AI summary

There is included (a) forming a film on a substrate by supplying a first processing gas to the substrate in a process container; (b) forming a first pre-coated film, which has a first thickness and has a material different from a material of the film formed in (a), in the process container by supplying a second processing gas into the process container in a state in which the substrate does not exist in the process container; and (c) forming a second pre-coated film, which has a second thickness smaller than the first thickness and has the same material as the material of the film formed in (a), on the first pre-coated film formed in the process container by supplying a third processing gas into the process container in the state in which the substrate does not exist in the process container.