Substrate Surface Treatment for Uniform Liquid Drying

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Solution Overview

Problem

Conventional liquid processing methods face issues with uneven drying of rinsing liquids on substrates with both water-repellent base surfaces and convex portions, leading to surface tension imbalances that can cause the convex portions to collapse.

Innovation Solution

A method and apparatus that selectively hydrophilize the base surface and water-repellent the convex portions before rinsing, ensuring uniform drying by using hydrophilizing and water-repellent liquids to control the surface tension and prevent coexistence of dry and wet areas during the drying process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the base surface and convex portions are both made water-repellent, then the convex portions are protected from collapse, but the rinsing liquid is not uniformly dried and surface tension imbalance occurs

Engineering Contradiction:
Improveprevention of convex portion collapseVSAvoiduniformity of drying
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention applies different surface properties to different regions: the base surface is made hydrophilic while the convex portions are made water-repellent. This local differentiation allows the rinsing liquid to be uniformly absorbed by the base surface while the convex portions remain protected from collapse by their water-repellent coating.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The surface treatment is performed in advance before the drying process. By pre-coating the base surface with a hydrophilic substance and the convex portions with a water-repellent substance, the system is prepared to ensure uniform drying and prevent collapse during the subsequent rinsing liquid removal process.

Inventive Principle:
Principle #10Preliminary action

2Object-affected harmful factors

If the rinsing liquid is supplied to a substrate with fully water-repellent surfaces, then the convex portions are protected, but uneven drying occurs causing surface tension imbalance

Engineering Contradiction:
Improveprotection from surface tension damageVSAvoiduniformity of liquid distribution
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

Different regions of the substrate are given different surface properties: the base surface is hydrophilic to ensure uniform spreading and absorption of the rinsing liquid, while the convex portions are water-repellent to protect them from collapse. This local quality differentiation resolves the contradiction between protection and uniform liquid distribution.

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If surface treatment is applied to make base surface hydrophilic and convex portions water-repellent, then uniform drying is achieved, but the process complexity increases

Engineering Contradiction:
Improveuniformity of dryingVSAvoidsurface treatment process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The surface treatment process is segmented into distinct steps: first treating the base surface to be hydrophilic, then treating the convex portions to be water-repellent. This segmentation allows for controlled application of different surface properties to different regions, achieving uniform drying while managing process complexity through systematic separation of treatment steps.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Prevents the collapse of convex portions by maintaining a balanced surface tension and ensuring uniform drying, as the hydrophilized base surface allows for even spreading and removal of the rinsing liquid, while water-repellent convex portions reduce the force causing collapse.

Implementation Method 1

processing a surface of the object to be processed such that the base surface of the object to be processed which is water-repellent becomes selectively hydrophilic

Methodology Applied
Scientific EffectHydrophilicity: Hydrophile

Implementation Method 2

the surfaces of the convex portions which are hydrophilic become selectively water-repellent

Methodology Applied
Scientific EffectWater repellency: Hydrophobe

Data Source

PatentUS8741070B2Liquid processing method, liquid processing apparatus and recording medium
Publication Date: 2014.06.03 TOKYO ELECTRON LTD
  • US8741070B2 patent drawing
  • US8741070B2 patent drawing
  • US8741070B2 patent drawing

AI summary

Disclosed are a liquid processing method, a liquid processing apparatus, and a recording medium that can prevent convex portions of a target substrate from collapsing when a rinsing liquid is dried. A base surface of a target substrate is hydrophilized and the surfaces of convex portions become water-repellent by surface-processing the target substrate which includes a main body, a plurality of convex portions protruding from the main body, and a base surface formed between the convex portions on the substrate main body. Next, a rinsing liquid is supplied to the target substrate which has been subjected to the surface processing. Thereafter, the rinsing liquid is removed from the target substrate.