Substrate Treatment Concentrates That Stay Stable Yet Pumpable

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Solution Overview

Problem

Existing skin and hair care compositions face challenges in maintaining stability at normal and elevated temperatures, preventing phase separation upon dilution, and providing sensory benefits like softness while allowing for the application of oil-soluble components, while ensuring skin compatibility and moisturization.

Innovation Solution

The composition includes hydrogenated and non-hydrogenated ethoxylated and propoxylated triglycerides of ricinoleic acid, ethoxylated and propoxylated glycerol fatty acid mono- and diesters, polyols, and glycerol fatty acid monoesters, with specific ethoxylation and propoxylation degrees, along with limited water content, to achieve flowability, stability, and sensory properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the composition contains high proportions of emulsifiers and additives to achieve stability and sensory properties, then the sensory properties and stability are improved, but the viscosity increases and pumpability deteriorates

Engineering Contradiction:
ImprovestabilityVSAvoidpumpability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by carefully controlling the degree of ethoxylation and propoxylation of the triglycerides and glycerol esters. By optimizing these chemical parameters (degree of ethoxylation ≥20, degree of propoxylation ≥20), the composition achieves both stability and low viscosity, resolving the contradiction between reliability and ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining multiple ethoxylated and propoxylated compounds with different molecular structures and properties. The composition includes ethoxylated triglycerides, propoxylated triglycerides, ethoxylated glycerol esters, and propoxylated glycerol esters, creating a synergistic mixture that provides both stability and flowability.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the composition is diluted with water to reduce viscosity and improve flowability, then the pumpability is improved, but phase separation occurs and stability deteriorates

Engineering Contradiction:
ImproveflowabilityVSAvoidstability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent uses ethoxylated and propoxylated compounds as intermediary substances that bridge the hydrophilic and lipophilic phases. These compounds with specific ethoxylation/propoxylation degrees act as mediators that prevent phase separation upon water dilution, maintaining stability while achieving good flowability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies parameter changes by controlling the water content at ≤20% and optimizing the ethoxylation/propoxylation degrees of the components. This parameter optimization ensures the composition remains stable even when diluted with water, preventing phase separation while maintaining pumpability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the composition is stored at elevated temperatures to accelerate processing and application, then the productivity is improved, but thermal stability deteriorates and component separation occurs

Engineering Contradiction:
Improveprocessing speedVSAvoidthermal stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses composite materials with ethoxylated and propoxylated triglycerides and glycerol esters that inherently resist thermal degradation. The synergistic combination of these stabilized compounds maintains composition integrity at elevated temperatures, enabling faster processing without component separation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by selecting compounds with specific ethoxylation and propoxylation degrees that provide thermal stability. These parameter-optimized compounds maintain their structural integrity at elevated temperatures, allowing accelerated processing while preventing thermal degradation and phase separation.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If conventional emulsifiers are used to achieve stability, then the stability is improved, but the composition becomes viscous and difficult to pump

Engineering Contradiction:
ImprovestabilityVSAvoidviscosity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent fundamentally changes the chemical parameters of the emulsifying agents by using ethoxylated and propoxylated compounds with specific degrees of modification (≥20). This parameter change transforms conventional viscous emulsifiers into low-viscosity, pumpable compounds that maintain stability, directly resolving the contradiction between reliability and device complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition is flowable, stable, and provides enhanced sensory properties, enabling effective moisturization and skin compatibility, allowing for the application of oil-soluble components without phase separation, even at elevated temperatures.

Implementation Method 1

The compositions contain as component (a) at least one compound selected from the group consisting of (a-1) hydrogenated and/or non-hydrogenated, ethoxylated and/or propoxylated triglycerides of ricinoleic acid... b. at least one ethoxylated and/or propoxylated glycerol fatty acid mono- and/or diester... These compounds function as emulsifiers to stabilize the composition and prevent phase separation

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

c. at least one polyol selected from the group consisting of glycerin, diglycerin, triglycerin, tetraglycerin, alkylene glycols and polyalkylene glycols... d. at least one glycerol fatty acid monoester... Another task was to provide compositions that make it possible to apply further components, in particular oil-soluble components, to the substrate. Another task was to provide substrates that enable skin-friendly cleaning of the skin and at the same time have a high level of skin compatibility. Of particular interest here were the moisturizing and moisture retention of the skin.

Methodology Applied
Scientific EffectHydrogen bonding:

Data Source

PatentEP2503982B1Concentrates for treating substrates
Publication Date: 2018.04.25 COGNIS IP MANAGEMENT GMBH
  • EP2503982B1 patent drawing
  • EP2503982B1 patent drawing
  • EP2503982B1 patent drawing

AI summary

The invention relates to compositions, containing a. at least one compound selected from the group consisting of (a-1) hydrogenated and/or non-hydrogenated, ethoxylated and/or propoxylated triglycerides of ricinoleic acid having a degree of ethoxylation and/or propoxylation of greater than or equal to 20, in particular from 20 to 60, (a-2) addition products of 2 to 50 mol ethylene oxide on sorbitan monoesters and/or diesters of saturated or unsaturated fatty acids having 6 to 22 carbon atoms, and (a-3) addition products of 2 to 50 mol ethylene oxide and 1 to 20 mol propylene oxide on alpha olefin epoxides having 8 to 22 C atoms and ring-opened with polyols , b. at least one ethoxylated and/or propoxylated glycerol fatty acid monoester and/or diester having a degree of ethoxylation of less than 20, preferably from 3 to 19, in particular from 3 to 15, c. at least one polyol selected from the group consisting of glycerol, diglycerol, triglycerol, tetraglycerol, alkylene glycols and polyalkylene glycols, d. at least one glycerol fatty acid monoester of the general formula (I), where R1 is a saturated or unsaturated, branched or linear group having 9 to 19 carbon atoms, and e. up to or equal to 20 wt% water. The invention further relates to the use of said compositions, and to substrates that are treated with the composition.