Continuous Succinic Acid Crystallization Stirring Control

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Solution Overview

Problem

Current methods for producing succinic acid lack efficiency and stability in achieving high-purity, uniform crystals with controlled particle size distribution, which is crucial for its use as a food additive and polymer starting material.

Innovation Solution

A continuous crystallization process in a tank equipped with a stirrer, where succinic acid is crystallized with controlled stirring conditions, seed crystals are introduced, and the process involves temperature management and pressure reduction to achieve narrow particle size distribution and high purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If batch crystallization is used with heat treatment, then crystal purity is improved, but production efficiency deteriorates

Engineering Contradiction:
Improvecrystal purityVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent implements continuous crystallization by continuously feeding succinic acid-containing liquid into the crystallization tank and continuously discharging the crystallized succinic acid, replacing the batch process. This continuous operation maintains high crystal purity through controlled stirring conditions (0.4-3 kW/m³) while significantly improving production efficiency and eliminating the need for repeated batch heating and cooling cycles

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent changes the operating parameters from batch to continuous mode, controlling the stirring power per unit volume within 0.4-3 kW/m³ range. This parameter optimization enables continuous crystallization to achieve both high purity crystals and high production efficiency simultaneously, resolving the contradiction between manufacturing precision and productivity

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If stirring conditions are optimized for narrow particle size distribution, then crystal uniformity is improved, but energy consumption increases

Engineering Contradiction:
Improveparticle size distributionVSAvoidstirring energy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the stirring power per unit volume to a specific range of 0.4-3 kW/m³, which is the critical parameter for achieving narrow particle size distribution. By controlling the stirring intensity within this optimized range during continuous crystallization, the patent achieves uniform crystal particles with excellent handleability while avoiding excessive energy consumption that would occur with higher stirring powers

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process efficiently produces high-purity succinic acid with uniform particle diameter and excellent handleability, ensuring stable and efficient crystallization.

Implementation Method 1

a crystallization tank equipped with a stirrer, wherein the crystallization is conducted continuously

Methodology Applied
Scientific EffectStirring: Stirring

Implementation Method 2

a crystallization step of producing solid succinic acid from a succinic-acid-containing liquid

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 3

the particle diameter and particle size distribution of succinic acid are regulated by regulating the stirring conditions and the degree of supersaturation

Methodology Applied
Scientific EffectSupersaturation: Supersaturation

Implementation Method 4

the resultant aqueous solution is cooled to cause crystallization

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 5

discharging the crystallized succinic acid continuously or intermittently from the crystallization tank

Methodology Applied
Scientific EffectPressure gradient: Pressure Gradient

Data Source

PatentEP2551256B1Method for producing succinic acid
Publication Date: 2020.05.06 MITSUBISHI CHEM CORP
  • EP2551256B1 patent drawingFigure 1
  • EP2551256B1 patent drawingFigure 2
  • EP2551256B1 patent drawingFigure 3

AI summary

Provided are processes for producing high-purity succinic acid from a succinic-acid-containing liquid through crystallization. The invention relates to a process for producing succinic acid which comprises crystallizing succinic acid from a succinic-acid-containing liquid with stirring in a crystallization tank equipped with a stirrer, wherein a power required for the stirring per unit volume of the succinic-acid-containing liquid in the crystallization tank is 0.4-3 kW/m3, and a process for producing succinic acid which comprises crystallizing succinic acid from a succinic-acid-containing liquid in a crystallization tank, wherein the process comprises a crystallization step in which the succinic acid that has crystallized is discharged continuously or intermittently from the crystallization tank and a succinic-acid-containing liquid is fed continuously or intermittently to the crystallization tank, to keep the liquid level of the crystallization tank so as to be within a given range.