Sugar-Based Binder Coated Refractories for Casting Mold Demolding

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Solution Overview

Problem

Conventional methods for manufacturing casting molds using phenol resin-based binder coated refractories result in environmental pollution due to the release of harmful gases and require excessive heat for demolding, complicating the process.

Innovation Solution

A method involving binder coated refractories with a sugar group binder, where the refractory aggregates are coated with a solid form binder containing sugar groups, and water vapor is supplied to condense and heat the binder, causing it to solidify and harden, thereby bonding the aggregates without generating harmful gases and facilitating easy demolding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If phenol resin-based binder is used to manufacture casting mold, then the casting mold has good dimensional accuracy and strength, but harmful gases are released causing environmental pollution

Engineering Contradiction:
Improvedimensional accuracyVSAvoidharmful gas emissions
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition parameter of the binder from phenol resin to sugar-based binder (such as sucrose, glucose, or starch). This parameter change fundamentally alters the decomposition behavior when exposed to molten metal, transforming the harmful gas emissions into harmless or minimally harmful products while maintaining the binding functionality required for dimensional accuracy.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the thermal decomposition characteristic of the binder into a beneficial process. Instead of releasing harmful phenolic gases, the sugar-based binder decomposes into water vapor and carbon dioxide, which are far less harmful. The decomposition also creates a porous structure that facilitates easier demolding, turning what would be a structural weakness into a functional advantage.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Temperature

If phenol resin-based binder is used in casting mold, then the binder has good heat resistance, but high-temperature heat over long period is required to decompose the binder for demolding

Engineering Contradiction:
Improveheat resistanceVSAvoiddemolding time
Core Design Contradiction:
TemperatureVSLoss of time

Solution Approach 1:

The invention changes the thermal decomposition temperature parameter of the binder from high (phenol resin requires prolonged high-temperature treatment) to low (sugar-based binder decomposes at moderate temperatures). This parameter change allows the binder to remain stable during casting but decompose readily during demolding, significantly reducing the time and energy required for mold removal.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a dynamic response in the binder's thermal behavior. The sugar-based binder maintains its binding strength at casting temperatures but automatically transitions to a decomposable state when exposed to the thermal conditions during demolding. This dynamic characteristic eliminates the need for prolonged high-temperature treatment required by phenol resin binders.

Inventive Principle:
Principle #15Dynamics

3Strength

If phenol resin-based binder is used, then the binder provides sufficient strength to the casting mold, but additional work is required to apply force for demolding the cast metal

Engineering Contradiction:
Improvemold strengthVSAvoiddemolding ease
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention changes the chemical composition parameter of the binder to sugar-based materials, which fundamentally alters the interaction between the mold and cast metal during demolding. The sugar-based binder decomposes and releases the cast metal without requiring excessive mechanical force, unlike phenol resin binders that maintain strong adhesion and require significant demolding effort.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the potential weakness of lower binder strength into a beneficial feature for demolding. The sugar-based binder's moderate strength is sufficient to maintain mold integrity during casting but naturally releases the cast metal during demolding, eliminating the need for excessive force application that would be required with stronger phenol resin binders.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Object-generated harmful factors

If sugar group binder is used instead of phenol resin, then harmful gas emissions are reduced, but the binder may have lower heat resistance

Engineering Contradiction:
Improveharmful gas emissionsVSAvoidheat resistance
Core Design Contradiction:
Object-generated harmful factorsVSTemperature

Solution Approach 1:

The invention changes the chemical composition parameter to sugar-based materials, which inherently have lower decomposition temperatures than phenol resin. However, this parameter change is compensated by optimizing the binder formulation and processing conditions to ensure sufficient thermal stability during casting while maintaining the environmental benefits of reduced harmful emissions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces environmental pollution by minimizing harmful gas emissions and simplifies the demolding process by allowing the casting mold to be broken easily with heat from the molten metal, improving mechanical strength and reducing the need for high-temperature decomposition.

Implementation Method 1

supplying water vapor to an inside of the casting flask, to change the sugar groups into the sugar groups having sticky paste condition according to condensation water developed as a result of transmission of heat of the water vapor

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

heating the binder coated refractories by a latent heat of the condensation of the water vapor to increase temperature of the binders with sugar groups having sticky paste condition

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

when pouring the molten metal into the casting mold, the heat in the molten metal degrades the phenol resin. Consequently, the gases such as phenol, xylenol, toluene, benzene, and methane are released

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentEP2476495B1Method of manufacturing casting mold using binder coated refractories
Publication Date: 2019.05.22 LIGNYTE CO LTD
  • EP2476495B1 patent drawingFigure 1A~1B
  • EP2476495B1 patent drawing
  • EP2476495B1 patent drawing

AI summary

The binder coated refractories comprises the refractory aggregates and the solid-form coating layer which comprises the sugar group as the binder and which is provided to the surface of the refractory aggregates. According to this, the sugar group is used as the binder for bonding the refractory aggregates. Further, even if the sugar group is thermally decomposed, the sugar group emits the carbon dioxide and the water. Therefore, there is little likelihood of emitting the harmful gas. Therefore, it is possible to reduce the environmental pollution. Further, the sugar group is thermally decomposed easily. Therefore, it is possible to manufacture the casting mold having the good breaking property.