Sugar-Based Surfactant for High-Temperature Well Fluids

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Solution Overview

Problem

The formation of stable emulsions between water and oil in oil and gas well treatment fluids, such as drilling muds and fracturing fluids, impedes hydrocarbon flow and is not effectively addressed by existing non-emulsifying agents due to their low thermal stability and flash points.

Innovation Solution

A well treatment fluid comprising an aqueous base and a sugar-based surfactant, specifically betaine functionalized alkyl polyglucosides, which acts as a non-emulsifying agent, rheology modifier, and chelating agent, providing thermal stability and biodegradability, effectively preventing and breaking emulsions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If commercially available non-emulsifying agents are added to prevent and break emulsions, then emulsion prevention and breaking is improved, but thermal stability deteriorates due to low flash points

Engineering Contradiction:
Improveemulsion prevention and breaking effectivenessVSAvoidthermal stability and flash point
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the chemical composition parameters of the surfactant from conventional petroleum-based structures to sugar-based structures (specifically alkyl polyglucosides with betaine functionalization). This fundamental parameter change in molecular structure inherently raises the flash point and improves thermal stability while maintaining or enhancing emulsion prevention and breaking effectiveness through the unique amphiphilic properties of the sugar-based molecules.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite surfactant molecule by combining sugar-based alkyl polyglucoside structures with betaine functional groups. This composite molecular structure integrates the thermal stability benefits of sugar-based compounds with the surfactant properties of betaine, achieving both high flash point and effective emulsion control in a single material.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If aqueous based fracturing fluids contain multiple components including polymers, gels, and fluid loss control agents, then fluid performance and control are improved, but emulsion formation is worsened due to stabilization by these components

Engineering Contradiction:
Improvefluid performance and control capabilityVSAvoidemulsion formation and stabilization
Core Design Contradiction:
Adaptability or versatilityVSObject-generated harmful factors

Solution Approach 1:

The sugar-based surfactant acts as a preliminary anti-action by being incorporated into the fracturing fluid formulation before emulsion formation occurs. It preemptively occupies the oil-water interface with its amphiphilic structure, preventing the stabilizing components (polymers, gels, fluid loss control agents) from effectively stabilizing emulsions. The surfactant creates a protective barrier that counteracts the emulsion-stabilizing tendency of other fluid components.

Inventive Principle:
Principle #9Preliminary anti-action

Solution Approach 2:

The invention converts the potentially harmful emulsion-stabilizing effect of multiple fluid components into a benefit by using the sugar-based surfactant to control and direct interfacial behavior. The surfactant harnesses the presence of multiple components and redirects their interaction at the oil-water interface, ensuring that rather than forming stable problematic emulsions, the components work together to maintain fluid stability and prevent unwanted emulsion formation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sugar-based surfactant effectively prevents and breaks emulsions at high temperatures, improving fluid rheology and enhancing hydrocarbon flow, thus improving hydrocarbon production by maintaining fluid stability and performance in high-temperature conditions.

Implementation Method 1

a sugar-based surfactant, specifically betaine functionalized alkyl polyglucosides, which acts as a non-emulsifying agent

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS11214725B2Sugar-based surfactant for well treatment fluids
Publication Date: 2022.01.04 HALLIBURTON ENERGY SERVICES INC
  • US11214725B2 patent drawing
  • US11214725B2 patent drawing
  • US11214725B2 patent drawing

AI summary

A well treatment fluid comprising an aqueous base fluid and a sugar-based surfactant is provided. The sugar-based surfactant includes at least one betaine functionalized alkyl polyglucoside. Also provided is a method of treating an oil and gas well.