Sulfatized Esteramine Composition for Clay Dispersion and Whiteness

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Solution Overview

Problem

Existing fabric and home care products, such as laundry and dishwashing detergents, lack improved clay dispersing properties and whiteness, as well as suds mileage, compared to esteramines without sulfate groups.

Innovation Solution

A process involving the reaction of alcohols with at least two hydroxy groups, lactams, and sulfuric acid to produce sulfatized esteramines, which are then incorporated into fabric and home care products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If esteramines without sulfate groups are used in fabric and home care products, then the product formulation is simpler, but the clay dispersing properties and whiteness performance are insufficient

Engineering Contradiction:
Improveproduct formulation simplicityVSAvoidclay dispersing properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies composite materials by combining esteramine structures with sulfate groups to create sulfatized esteramines. This composite structure integrates the surfactant properties of esteramines with the dispersing capabilities of sulfate groups, achieving both good clay dispersing properties and improved whiteness performance while maintaining formulation feasibility

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by modifying the chemical structure of esteramines through sulfatization. By introducing sulfate groups (-OSO3H) at specific positions on the esteramine molecules, the patent alters the chemical parameters to enhance clay dispersing properties and whiteness performance without completely redesigning the formulation

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If esteramines without sulfate groups are used in fabric and home care products, then the manufacturing process is simpler, but the suds mileage is insufficient

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidsuds mileage
Core Design Contradiction:
Ease of manufactureVSDuration of action of moving object

Solution Approach 1:

The patent creates composite surfactant molecules by combining esteramine backbones with sulfate group attachments. This composite structure provides both the surfactant functionality needed for suds generation and the sulfate group contributions to suds stability and mileage, achieving improved duration of action without overly complicating the manufacturing process

Inventive Principle:
Principle #40Composite materials

3Reliability

If sulfatized esteramines are incorporated into fabric and home care products, then clay dispersing properties and whiteness performance are improved, but the product formulation becomes more complex

Engineering Contradiction:
Improveclay dispersing propertiesVSAvoidproduct formulation complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent manages formulation complexity by making targeted parameter changes - specifically introducing sulfate groups at controlled positions and ratios on esteramine molecules. This approach achieves improved clay dispersing properties and whiteness performance while limiting the increase in formulation complexity through systematic modification rather than complete reformulation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sulfatized esteramines exhibit enhanced clay dispersing properties and improved whiteness, as well as increased suds mileage, compared to esteramines without sulfate groups.

Implementation Method 1

reacting at least one alcohol containing at least two hydroxy groups (compound (A)) with at least one lactam (compound (B)) and with sulfuric acid (compound (C))

Methodology Applied
Scientific EffectEsterification: Chemical Bonding

Implementation Method 2

reacting at least one alcohol containing at least two hydroxy groups (compound (A)) with at least one lactam (compound (B)) and with sulfuric acid (compound (C)) to produce sulfatized esteramines

Methodology Applied
Scientific EffectSulfation: Chemical Bonding

Data Source

PatentEP3933017B1Fabric and home care product comprising a sulfatized esteramine
Publication Date: 2026.04.08 PROCTER & GAMBLE CO
  • EP3933017B1 patent drawing
  • EP3933017B1 patent drawing
  • EP3933017B1 patent drawing

AI summary

The present invention relates to fabric and home care products comprising sulfatized esteramines obtainable by a process comprising step a), wherein at least one alcohol containing at least two hydroxy groups (compound (A)) is reacted with at least one lactam (compound (B)) and with sulfuric acid (compound (C)).