Sulfobetaine Monomer Polymerization Composition Moisture Control

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Solution Overview

Problem

The storage stability of sulfobetaine monomers is compromised in high-temperature environments, leading to discoloration of cured films due to uncontrolled moisture levels, which affects their industrial applications such as in coatings and printing.

Innovation Solution

A composition for polymerization is developed with a specific sulfobetaine monomer and controlled moisture content between 3% to 10% by mass, which inhibits discoloration and enhances storage stability, comprising the monomer, water, and optionally ethylenically unsaturated groups, formulated to maintain stability during high-temperature storage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If sulfobetaine monomer is stored as powder in high-temperature environment, then storage stability deteriorates and discoloration occurs, but controlling moisture content adds complexity to storage and handling

Engineering Contradiction:
Improvestorage stabilityVSAvoidmoisture control complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention changes the moisture content parameter of the sulfobetaine monomer from uncontrolled or low levels to a specific range of 3% to 10% by mass. This parameter change resolves the technical contradiction by improving storage stability and preventing discoloration at high temperatures, while the controlled moisture range avoids excessive complexity in storage and handling procedures.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If moisture content is not controlled in sulfobetaine monomer, then storage stability improves and handling becomes simpler, but discoloration of cured films occurs under high-temperature conditions

Engineering Contradiction:
Improvehandling simplicityVSAvoiddiscoloration
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The invention applies parameter change by establishing a specific moisture content range of 3% to 10% by mass in the sulfobetaine monomer. This resolves the contradiction by preventing discoloration of cured films under high-temperature conditions while maintaining relatively simple handling procedures, as the moisture control is achieved through standard manufacturing processes rather than complex operational controls.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3260477B1Composition for polymerization, method for producing same, coating composition containing same, method for producing coating composition containing said compositions, and method for producing coating
Publication Date: 2022.08.24 FUJIFILM CORP
  • EP3260477B1 patent drawingFigure 1
  • EP3260477B1 patent drawing
  • EP3260477B1 patent drawing

AI summary

[Problem] Provided is a composition for polymerization that makes it possible to improve the storage stability in high-temperature environments when a specific sulfobetaine monomer is stored as a powder as well as to suppress discoloration when a cured coating film is made, and a method for producing said composition. Also provided are a coating composition containing said composition for polymerization, a method for producing a coating composition in which said compositions are used, and a method for producing a coating. [Solution] A composition for polymerization containing a monomer represented by formula (I) and water, wherein the composition for polymerization has a water content of from 3% by mass to less than 10% by mass. (R represents a hydrogen atom or a methyl group.)