Sulfonated Vegetable Oil Salts for Brine Lubricity

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Solution Overview

Problem

High density brines used in drilling and completion fluids are ineffective in providing constant lubricity during high shear conditions, particularly in deep and horizontal wells, and existing lubricating additives are not compatible with brine-based fluids, pose environmental concerns, and are costly.

Innovation Solution

Incorporating a water-soluble or water-dispersible salt of sulfonated vegetable oil, such as sodium or potassium salt of sulfonated castor oil, into drilling or completion fluids, along with a surfactant like ethoxylated alcohol and a freezing point depressant, to reduce friction and enhance lubricity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If high density brines are used in drilling and completion fluids, then the fluid density and hydrostatic pressure are increased, but the lubricity under high shear conditions deteriorates

Engineering Contradiction:
Improvehydrostatic pressureVSAvoidlubricity
Core Design Contradiction:
Stress or pressureVSEase of operation

Solution Approach 1:

The invention changes the chemical composition parameters of the brine by adding sulfonated vegetable oil salts and surfactants. This modifies the fluid's rheological properties to provide constant lubricity under high shear conditions while maintaining the required density and hydrostatic pressure for deep well operations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite brine formulation by combining high density brine with sulfonated vegetable oil salts and surfactants. This composite material integrates the density-providing capability of brine with the lubricity-providing capability of the sulfonated oil compounds, resolving the contradiction between hydrostatic pressure and lubricity

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional lubricating additives are used in brine-based drilling fluids, then the lubricity is improved, but compatibility with brine and environmental friendliness deteriorate

Engineering Contradiction:
ImprovelubricityVSAvoidenvironmental harm
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The invention uses biodegradable sulfonated vegetable oil salts derived from renewable resources instead of persistent synthetic lubricants. These environmentally friendly additives provide the needed lubricity but break down naturally, eliminating long-term environmental contamination concerns while maintaining effective lubrication during the drilling operation

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention changes the chemical nature of lubricating additives from conventional synthetic compounds to sulfonated vegetable oil salts. This parameter change in additive composition simultaneously achieves compatibility with brine-based fluids and environmental friendliness through biodegradability and renewable sourcing

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional lubricating additives are used in drilling fluids, then the lubricity is improved, but the cost increases

Engineering Contradiction:
ImprovelubricityVSAvoidcost
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The invention replaces expensive conventional lubricating additives with cost-effective sulfonated vegetable oil salts. These additives are derived from abundant renewable resources and can be produced more economically, reducing the overall cost of drilling fluid formulations while maintaining effective lubricity performance

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces the coefficient of friction by up to 35% and is environmentally friendly, effective in high density brines, and stable up to 300°F, preventing differential sticking and reducing torque and drag.

Implementation Method 1

The lubricating agent is typically a sodium, potassium, calcium, magnesium or ammonium salt. In a preferred embodiment, the lubricating agent is a salt of sulfonated (sulfated) castor oil

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 2

In addition to the sulfonated (sulfated) vegetable oil, a surfactant may further be incorporated into the drilling fluid or completion fluid which is capable of enhancing the solubility of the salt

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 3

Further, a freezing point depressant may also be incorporated into the drilling fluid or completion fluid

Methodology Applied
Scientific EffectFreezing point depression: Freezing

Data Source

PatentUS8071510B2Method of increasing lubricity of brine-based drilling fluids and completion brines
Publication Date: 2011.12.06 BAKER HUGHES CO

AI summary

The lubricity of a drilling fluid or a completion fluid may be increased by incorporating into the fluid a water-soluble or water-dispersible salt of a sulfonated (sulfated) vegetable oil or a derivative thereof, such as a sulfonated (sulfated) castor oil. Suitable derivatives include the sodium, potassium, calcium, magnesium or ammonium salt. A non-ionic or anionic surfactant which is capable of enhancing the solubility of the salt may further be incorporated into the drilling fluid or completion fluid.