Sulfoperoxycarboxylic Acid Composition for Stable Low-Odor Bleaching

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Solution Overview

Problem

Conventional peroxycarboxylic acids have limitations such as limited storage stability, water insolubility, and an unpleasant odor, which restrict their use as effective antimicrobial and bleaching agents.

Innovation Solution

Development of novel sulfoperoxycarboxylic acids that are storage stable, low or odor-free, and water soluble, derived from non-petroleum based renewable oils, suitable for use as bleaching, antimicrobial, and coupling agents, including low-temperature bleaches and pH-optimized peroxygen bleaches.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional peroxycarboxylic acids are used as bleaching and antimicrobial agents, then they provide effective antimicrobial and bleaching properties, but they have limited storage stability, water insolubility, and unpleasant odor

Engineering Contradiction:
Improvestorage stabilityVSAvoidunpleasant odor
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces sulfonic acid groups into the peroxycarboxylic acid structure, fundamentally changing the chemical parameters of the molecule. This structural modification transforms the compound from hydrophobic and unstable to hydrophilic and storage-stable, while simultaneously eliminating the unpleasant odor associated with conventional peroxycarboxylic acids

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite molecular structure combining the peroxycarboxylic acid functional group with sulfonic acid groups. This composite structure integrates the desirable bleaching and antimicrobial properties of peroxycarboxylic acids with the water solubility, stability, and low-odor characteristics of sulfonic acid compounds

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional peroxycarboxylic acids are used, then they exhibit antimicrobial and bleaching activity, but they are water insoluble and have limited storage stability

Engineering Contradiction:
Improvewater solubilityVSAvoidstorage stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The sulfonation of the peroxycarboxylic acid structure fundamentally alters its physical and chemical parameters. The introduction of polar sulfonic acid groups dramatically increases water solubility while the resulting salt forms exhibit enhanced storage stability, resolving the contradiction between solubility and stability

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional peroxycarboxylic acids are used as bleaching agents, then they provide effective bleaching, but they have unpleasant odor and limited storage stability

Engineering Contradiction:
Improvebleaching efficacyVSAvoidunpleasant odor
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The chemical structure modification through sulfonation changes the volatility and odor profile of the compound while preserving the reactive peroxycarboxylic acid group responsible for bleaching activity. The sulfonic acid groups do not interfere with the bleaching mechanism but eliminate the unpleasant odor

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention effectively extracts or removes the harmful odor property from the peroxycarboxylic acid molecule by adding sulfonic acid groups, separating the desirable bleaching function from the undesirable odor characteristic

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sulfoperoxycarboxylic acids demonstrate enhanced stability, solubility, and reduced odor, enabling their use in various applications like textile bleaching, food processing, and surface disinfection while maintaining antimicrobial efficacy.

Implementation Method 1

Peroxycarboxylic acids are known for use as antimicrobials and bleaching agents

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS10017720B2Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
Publication Date: 2018.07.10 ECOLAB USA INC
  • US10017720B2 patent drawing
  • US10017720B2 patent drawing
  • US10017720B2 patent drawing

AI summary

The present invention relates to novel sulfoperoxycarboxylic acid compounds, and methods for making and using them. The sulfoperoxycarboxylic compounds of the invention are storage stable, water soluble and have low to no odor. Further, the compounds of the present invention can be formed from non-petroleum based renewable materials. The compounds of the present invention can be used as antimicrobials, and bleaching agents. The compounds of the present invention are also suitable for use as coupling agents.