Sulfoperoxycarboxylic Acids for Stable Water-Soluble Bleaching

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional peroxycarboxylic acids have limitations such as limited storage stability, water insolubility, and an unpleasant odor, which restrict their use as effective antimicrobial and bleaching agents.

Innovation Solution

Development of sulfoperoxycarboxylic acids that are storage stable, low or odor-free, and water soluble, derived from non-petroleum based renewable oils, suitable for use as bleaching, antimicrobial, and coupling agents, including low-temperature bleaches and pH-optimized peroxygen bleaches for textiles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional peroxycarboxylic acids are used as bleaching and antimicrobial agents, then they provide effective antimicrobial and bleaching properties, but they have limited storage stability, water insolubility, and unpleasant odor

Engineering Contradiction:
Improvestorage stabilityVSAvoidwater solubility
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces sulfonate groups (-SO3Na) into the peroxycarboxylic acid structure, fundamentally changing the chemical parameters of the molecule. This structural modification transforms the compound from water-insoluble to water-soluble while maintaining stability and eliminating odor, directly resolving the technical contradictions

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional peroxycarboxylic acids are used, then they exhibit antimicrobial and bleaching activity, but they have limited storage stability

Engineering Contradiction:
Improvestorage stabilityVSAvoideffective concentration
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention creates a composite molecular structure combining the peroxycarboxylic acid functional group with sulfonate groups and hydrocarbon chains. This composite structure integrates the antimicrobial/bleaching properties of peracids with the stability and solubility properties of sulfonated compounds, achieving both high stability and effective concentration

Inventive Principle:
Principle #40Composite materials

3Object-generated harmful factors

If conventional peroxycarboxylic acids are used as bleaching agents, then they provide bleaching action, but they have unpleasant odor

Engineering Contradiction:
ImproveodorVSAvoidbleaching efficiency
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The sulfonation modification changes the physical and chemical parameters of the peroxycarboxylic acid, including odor characteristics. The resulting sulfoperoxycarboxylic acid compounds are described as odorless or having minimal odor while maintaining full bleaching efficiency, thus resolving this contradiction

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If conventional peroxycarboxylic acids are used, then they provide antimicrobial properties, but they have water insolubility

Engineering Contradiction:
Improvewater solubilityVSAvoidantimicrobial efficacy
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

By introducing ionic sulfonate groups into the molecular structure, the patent fundamentally changes the solubility parameters of the compound. The resulting sulfoperoxycarboxylic acids are highly water-soluble while retaining antimicrobial efficacy, as the active peroxycarboxylic acid functional group remains intact

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sulfoperoxycarboxylic acids demonstrate enhanced stability, solubility, and odorlessness, enabling their use as effective bleaching and antimicrobial agents, particularly in low-temperature applications and with alkaline detergents, while being textile tolerant and safe for wool and cotton.

Implementation Method 1

Peroxycarboxylic acids are known for use as antimicrobials and bleaching agents

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS8809392B2Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
Publication Date: 2014.08.19 ECOLAB USA INC
  • US8809392B2 patent drawing
  • US8809392B2 patent drawing
  • US8809392B2 patent drawing

AI summary

The present invention relates to novel sulfoperoxycarboxylic acid compounds, and methods for making and using them. The sulfoperoxycarboxylic compounds of the invention are storage stable, water soluble and have low to no odor. Further, the compounds of the present invention can be formed from non-petroleum based renewable materials. The compounds of the present invention can be used as antimicrobials, and bleaching agents. The compounds of the present invention are also suitable for use as coupling agents.