Sulfur-Based Aqueous Compositions With Sorbent Odor Removal
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Solution Overview
Problem
Existing methods fail to permanently remove the unpleasant refinery odor and brown color from sulfur-based compounds produced from industrial gas streams containing hydrogen sulfide, sulfur dioxide, and ammonia, which are used in fertilizer production, as the odor often returns after a short period.
Innovation Solution
Aqueous compositions are prepared from gas streams containing hydrogen sulfide, sulfur dioxide, and ammonia, treated with a sorbent material such as macroporous hydrophobic nonfunctionalized resin or granular activated carbon to reduce refinery hydrocarbons below the olfactive detection limit, maintaining odorlessness for extended periods.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Object-affected harmful factors
If traditional methods are used to remove refinery odor from sulfur-based compounds, then the odor is temporarily removed, but the odor returns after a short period
Solution Approach 1:
The patent applies local quality by using a two-stage treatment process where different treatment methods are applied to different aspects of the odor removal problem. The first stage uses a specific treatment method for initial odor removal, while the second stage applies a different treatment to maintain long-term odorlessness, addressing both temporary and persistent odor concerns with specialized approaches for each stage.
Solution Approach 2:
The patent implements preliminary action by performing an initial treatment step before the final product is produced. This preliminary treatment removes the bulk of the refinery odor and contaminants from the sulfur-based compounds before further processing, preventing odor recurrence by addressing the root cause early in the production process rather than attempting to mask symptoms later.
2Object-affected harmful factors
If sorbent material is used to treat aqueous compositions, then refinery hydrocarbons are reduced below olfactive detection limit, but the treatment process complexity increases
Solution Approach 1:
The patent employs porous materials, specifically sorbent materials with high surface area and porosity, to efficiently adsorb refinery hydrocarbons from the aqueous compositions. These porous sorbents provide extensive surface area for contaminant absorption while maintaining a relatively simple treatment process structure, achieving effective hydrocarbon removal without proportionally increasing system complexity.
Solution Approach 2:
The patent utilizes disposable or easily replaceable sorbent materials that can be discarded after a single use or after reaching saturation capacity. This approach simplifies the overall treatment system design by eliminating the need for complex regeneration or recovery systems, accepting that the sorbent itself is a consumable component that provides effective odor and contaminant removal through its service life.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The compositions remain free of refinery odor and color for at least 24 hours, providing transparent and odorless products suitable for agricultural use, despite being derived from contaminated gas streams.
Implementation Method 1
treated with a sorbent material such as macroporous hydrophobic nonfunctionalized resin or granular activated carbon to reduce refinery hydrocarbons below the olfactive detection limit
Data Source
AI summary
An aqueous composition comprises at least one oxidizable sulfur-based compound. A concentrated extract of the aqueous composition includes a gas chromatography/mass spectrometry-detectable amount of contaminating refinery hydrocarbons but the aqueous composition is free of refinery odor when stored for at least 24 hours at room temperature and 60% relative humidity. The aqueous compositions are prepared from a gas stream obtained from a petroleum refinery process, a coke oven, or the like, containing at least about 4 mol %, more specifically about 15 mol %, of hydrogen sulfide (H2S) and/or sulfur dioxide (SO2) and/or ammonia (NH3), and at least about 0.1 mol % of contaminating refinery hydrocarbons. The aqueous compositions are suitable for use in fertilizers, mining and industrial applications.


