Sulfur-Based Aqueous Compositions With Sorbent Odor Removal

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing methods fail to permanently remove the unpleasant refinery odor and brown color from sulfur-based compounds produced from industrial gas streams containing hydrogen sulfide, sulfur dioxide, and ammonia, which are used in fertilizer production, as the odor often returns after a short period.

Innovation Solution

Aqueous compositions are prepared from gas streams containing hydrogen sulfide, sulfur dioxide, and ammonia, treated with a sorbent material such as macroporous hydrophobic nonfunctionalized resin or granular activated carbon to reduce refinery hydrocarbons below the olfactive detection limit, maintaining odorlessness for extended periods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional methods are used to remove refinery odor from sulfur-based compounds, then the odor is temporarily removed, but the odor returns after a short period

Engineering Contradiction:
Improverefinery odorVSAvoidduration of odorlessness
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of stationary object

Solution Approach 1:

The patent applies local quality by using a two-stage treatment process where different treatment methods are applied to different aspects of the odor removal problem. The first stage uses a specific treatment method for initial odor removal, while the second stage applies a different treatment to maintain long-term odorlessness, addressing both temporary and persistent odor concerns with specialized approaches for each stage.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements preliminary action by performing an initial treatment step before the final product is produced. This preliminary treatment removes the bulk of the refinery odor and contaminants from the sulfur-based compounds before further processing, preventing odor recurrence by addressing the root cause early in the production process rather than attempting to mask symptoms later.

Inventive Principle:
Principle #10Preliminary action

2Object-affected harmful factors

If sorbent material is used to treat aqueous compositions, then refinery hydrocarbons are reduced below olfactive detection limit, but the treatment process complexity increases

Engineering Contradiction:
Improverefinery hydrocarbon contentVSAvoidtreatment process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent employs porous materials, specifically sorbent materials with high surface area and porosity, to efficiently adsorb refinery hydrocarbons from the aqueous compositions. These porous sorbents provide extensive surface area for contaminant absorption while maintaining a relatively simple treatment process structure, achieving effective hydrocarbon removal without proportionally increasing system complexity.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent utilizes disposable or easily replaceable sorbent materials that can be discarded after a single use or after reaching saturation capacity. This approach simplifies the overall treatment system design by eliminating the need for complex regeneration or recovery systems, accepting that the sorbent itself is a consumable component that provides effective odor and contaminant removal through its service life.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compositions remain free of refinery odor and color for at least 24 hours, providing transparent and odorless products suitable for agricultural use, despite being derived from contaminated gas streams.

Implementation Method 1

treated with a sorbent material such as macroporous hydrophobic nonfunctionalized resin or granular activated carbon to reduce refinery hydrocarbons below the olfactive detection limit

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12492153B2Products prepared from waste gas streams containing H<sub>2</sub>S, SO<sub>2</sub>, and/or NH<sub>3</sub>
Publication Date: 2025.12.09 TESSENDERLO GROUP NV
  • US12492153B2 patent drawing
  • US12492153B2 patent drawing
  • US12492153B2 patent drawing

AI summary

An aqueous composition comprises at least one oxidizable sulfur-based compound. A concentrated extract of the aqueous composition includes a gas chromatography/mass spectrometry-detectable amount of contaminating refinery hydrocarbons but the aqueous composition is free of refinery odor when stored for at least 24 hours at room temperature and 60% relative humidity. The aqueous compositions are prepared from a gas stream obtained from a petroleum refinery process, a coke oven, or the like, containing at least about 4 mol %, more specifically about 15 mol %, of hydrogen sulfide (H2S) and/or sulfur dioxide (SO2) and/or ammonia (NH3), and at least about 0.1 mol % of contaminating refinery hydrocarbons. The aqueous compositions are suitable for use in fertilizers, mining and industrial applications.