Sulfur Oxide Luminescent Material Core-Shell Structure
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Solution Overview
Problem
Traditional sulfur oxide luminescent materials have low luminescent efficiency, limiting their application in field emission devices despite their chemical stability and other advantageous properties.
Innovation Solution
A sulfur oxide luminescent material with a porous structure and a core-shell structure formed by coating metal nanoparticles such as Ag, Au, Pt, or Cu inside, where Eu3+ is doped in Ln2-xO2S, enhancing internal quantum efficiency and luminescent efficiency through plasma effects without altering the emission wavelength, and a method for preparing this material involving hydrothermal carbon coating and calcination.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If traditional sulfur oxide luminescent materials are used, then chemical stability is maintained, but luminescent efficiency is low
Solution Approach 1:
The patent creates a core-shell composite structure where metal nanoparticles (core) are coated with sulfur oxide luminescent material (shell). This composite structure combines the plasma generation capability of metals with the luminescent properties of sulfur oxide, achieving both chemical stability and high luminescent efficiency. The metal core generates plasma under electron beam irradiation, which then excites the luminescent material shell to emit light.
Solution Approach 2:
The invention applies different functional properties to different parts of the structure: the metal nanoparticle core provides plasma generation and energy conversion functions, while the sulfur oxide shell provides luminescent emission and chemical stability. This local differentiation of functions allows each component to optimize its performance for its specific role, resolving the contradiction between stability and efficiency.
2Loss of energy
If more rare earth elements are added to improve luminescent efficiency, then emission intensity increases, but material cost increases
Solution Approach 1:
The patent replaces the traditional approach of relying solely on rare earth element concentration for luminescent efficiency with a plasma-based energy conversion mechanism. The metal nanoparticle core generates plasma that efficiently transfers energy to the luminescent material, substituting the need for high rare earth content with a more efficient energy conversion pathway. This reduces rare earth element requirements while maintaining or improving luminescent efficiency.
Solution Approach 2:
The invention changes the energy conversion parameters by introducing plasma generation through metal nanoparticles. Instead of relying on direct rare earth element excitation, the system uses plasma as an intermediate energy carrier, fundamentally changing how energy is transferred and converted. This parameter change enables high luminescent efficiency with reduced rare earth element content.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The approach significantly increases luminescent efficiency while reducing the amount of rare earth elements needed, lowering costs and maintaining the wavelength of emitted light, making the material suitable for industrial production and broad applications.
Implementation Method 1
By introducing a metal nanoparticle, the luminescent efficiency can be enhanced by plasma effect
Implementation Method 2
Ln2-xO2S:Eu3+ is a sulfur oxide luminescent material doped with rare earth element
Data Source
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AI summary
Provided is a sulfur oxide luminescent material. The luminescent material has a general chemical formula of Ln2-xO2S:Eux3+@My, wherein@ is coating, Eu is doped in Ln2-xO2S, Ln2-xO2S:Eux3+ has a porous structure, and M is located in pores of the Ln2-xO2S:Eux3+. In the sulfur oxide luminescent material, metal nano particles coating is used to form a core-shell structure, which increases luminescent efficiency of the sulfur oxide luminescent material in a same excitation condition; in addition, a hollow structure is formed between a core and a shell layer of the sulfur oxide luminescent material, which effectively reduces usage of rare earth elements in the shell layer and lowers cost of the luminescent material. Also provided is a preparation method for the sulfur oxide luminescent material.