Sunblock Composition Bicontinuous Microemulsion UV Protection

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Solution Overview

Problem

Conventional sunscreen compositions face challenges in achieving high ultraviolet protection and stability while maintaining a refreshing, dewy texture, as well as uniform coating and absorption, due to limitations in the type and quantity of ultraviolet absorbents that can be used in emulsified systems.

Innovation Solution

A sunscreen composition utilizing a bicontinuous microemulsion phase, comprising specific surfactants, water, an oil component, and ultraviolet absorbents, is formulated to achieve a thermodynamically stable and optically isotropic solution that enhances ultraviolet protection and skin absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a large quantity of oil soluble ultraviolet absorbent is blended into oil-in-water emulsified composition, then ultraviolet protection ability is improved, but the emulsion stability deteriorates and texture becomes sticky

Engineering Contradiction:
Improveultraviolet protection abilityVSAvoidemulsion stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent changes the physical state parameter of the system from conventional emulsion to microemulsion phase. By adjusting the surfactant type and concentration, along with oil and water ratios, the system transitions to a microemulsion state that can stably accommodate high concentrations of oil soluble ultraviolet absorbents without phase separation or stickiness, thus resolving the contradiction between UV protection and emulsion stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite surfactant system comprising both ionic and nonionic surfactants. This composite approach creates a microemulsion phase that combines the benefits of both surfactant types, enabling high oil soluble UV absorbent loading while maintaining system stability and avoiding the sticky texture associated with conventional emulsions.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If water soluble ultraviolet absorbent is added to maintain low oil soluble absorbent ratio, then ultraviolet protection ability is improved, but salt concentration increases and emulsification stability deteriorates

Engineering Contradiction:
Improveultraviolet protection abilityVSAvoidemulsification stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent changes the system parameter from conventional emulsion to microemulsion phase by adjusting surfactant composition and ratios. This phase transition eliminates the need for high salt concentrations to stabilize the system, allowing water soluble UV absorbents to be incorporated without compromising emulsification stability, thus resolving the contradiction between UV protection and emulsion stability.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If oil component quantity is increased in water-in-oil emulsified composition, then ultraviolet protection ability is improved, but texture becomes sticky and oiliness increases

Engineering Contradiction:
Improveultraviolet protection abilityVSAvoidspreadability
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent changes the system from conventional water-in-oil emulsion to microemulsion phase. This phase transition allows high oil component concentrations to be achieved while maintaining low viscosity and excellent spreadability, eliminating the sticky and oily texture problems associated with conventional water-in-oil emulsions.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If highly polar ultraviolet absorbent is dissolved in oil phase of water-in-oil emulsion, then ultraviolet protection ability is improved, but long term stability deteriorates due to separation and aggregation

Engineering Contradiction:
Improveultraviolet protection abilityVSAvoidlong term stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent changes the system parameter from conventional emulsion to microemulsion phase. In this microemulsion state, highly polar ultraviolet absorbents can be dissolved in the oil phase without undergoing separation and aggregation over time, as the microemulsion structure provides thermodynamic stability that prevents phase separation, thus resolving the contradiction between UV protection and long term stability.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP2543356B1Sunblock composition
Publication Date: 2017.01.04 SHISEIDO CO LTD
  • EP2543356B1 patent drawingFigure 1~2
  • EP2543356B1 patent drawingFigure 3~4
  • EP2543356B1 patent drawingFigure 5~6

AI summary

The present invention provides a sunscreen composition comprising (a) a surfactant, (b) water, (c) an oil component, and (d) a water soluble ultraviolet absorbent and/or oil soluble ultraviolet absorbent that is in the bicontinuous microemulsion phase at 25°C. The object of the present invention is to obtain a sunscreen composition that is superior in terms of the ultraviolet protection ability and the tactile sensation during use. Furthermore, its object is to provide a sunscreen composition composed of a transparent bicontinuous microemulsion phase that spreads well when applied on the skin, is superior in terms of the coating film uniformity and absorption into the skin.